CH4Si


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH3Si- + Hydrogen cation = CH4Si

By formula: CH3Si- + H+ = CH4Si

Quantity Value Units Method Reference Comment
Δr364.2 ± 5.0kcal/molD-EABengali and Leopold, 1992gas phase
Quantity Value Units Method Reference Comment
Δr356.0 ± 5.1kcal/molH-TSBengali and Leopold, 1992gas phase

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to CH4Si+ (ion structure unspecified)

De-protonation reactions

CH3Si- + Hydrogen cation = CH4Si

By formula: CH3Si- + H+ = CH4Si

Quantity Value Units Method Reference Comment
Δr364.2 ± 5.0kcal/molD-EABengali and Leopold, 1992gas phase
Quantity Value Units Method Reference Comment
Δr356.0 ± 5.1kcal/molH-TSBengali and Leopold, 1992gas phase

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bengali and Leopold, 1992
Bengali, A.A.; Leopold, D.G., Negative Ion Photoelectron Spectroscopy of CH2=SiH and CH3Si, J. Am. Chem. Soc., 1992, 114, 23, 9192, https://doi.org/10.1021/ja00049a064 . [all data]


Notes

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