Bis(acetylacetonato)zinc
- Formula: C10H14O4Zn
- Molecular weight: 263.60
- IUPAC Standard InChIKey: CYDXJXDAFPJUQE-FDGPNNRMSA-L
- CAS Registry Number: 14024-63-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Zinc, bis(2,4-pentanedionato)-; Zinc, bis(2,4-pentanedionato-O,O')-, (T-4)-; Bis(2,4-pentanedionato)zinc; Zinc acetoacetonate; Zinc acetylacetonate; Zinc acetylacetone chelate; Zinc bis(acetylacetonate); Zinc bis(acetylacetone); Zinc(II) acetylacetonate; Zinc, bis(2,4-pentanedionato)di-; (CH3COCHCOCH3)2Zn; Zinc 2,4-pentanedionate; Zinc bis(2,4-pentanedionate); Zinc, bis(2,4-pentanedionato-O,O')-; bis(pentane-2,4-dionato-O,O')zinc
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Phase change data
Go To: Top, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 400.5 | K | N/A | Grinberg, Lazarev, et al., 1986 | Uncertainty assigned by TRC = 0.1 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 32. ± 2. | kcal/mol | C | Murata, Sakiyama, et al., 1985 | See also Ribeiro da Silva, Pilcher, et al., 1988.; AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
4.3499 | 400.5 | Grinberg, Lazarev, et al., 1986 | DH |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
10.9 | 400.5 | Grinberg, Lazarev, et al., 1986 | DH |
IR Spectrum
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | COBLENTZ SOCIETY Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | MAC KENZIE CHEMICAL WORKS, INC., LONG ISLAND, NEW YORK |
Source reference | COBLENTZ NO. 4885 |
Date | Not specified, most likely prior to 1970 |
State | SOLID (KBr WAFER) |
Instrument | BECKMAN IR-4 (HYBRID PRISM-GRATING) |
Resolution | 4 |
Sampling procedure | TRANSMISSION |
Data processing | DIGITIZED BY NIST FROM HARD COPY |
Melting point | 138 C MW 263.59 |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 12767 |
References
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Grinberg, Lazarev, et al., 1986
Grinberg, Ya.Kh.; Lazarev, V.B.; Zavernyaev, A.Yu.; Shreider, V.A.; Chepik, S.D.,
Enthalpies of fusion of aluminium(III), chromium(III), zirconium(IV), and zinc(II) acetylacetonates,
Zhur. Fiz. Khim., 1986, 60, 1044. [all data]
Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S.,
Sublimation calorimetric studies using a calvet microcalorimeter,
Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8
. [all data]
Ribeiro da Silva, Pilcher, et al., 1988
Ribeiro da Silva, Manuel A.V.; Pilcher, Geoffrey; Irving, Roger J.,
Standard enthalpies of formation of the bis(pentane-2,4-dionato) complexes of the Group II metals: Be, Mg, Ca, Sr, Ba, Zn, Cd, and Hg. The mean (metal-oxygen) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1988, 20, 1, 95-102, https://doi.org/10.1016/0021-9614(88)90213-3
. [all data]
Notes
Go To: Top, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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