Diethylzinc

• Formula: C₄H₁₀Zn
• Molecular weight: 123.50
• IUPAC Standard InChI: InChI=1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3; Copy

  
• IUPAC Standard InChIKey: HQWPLXHWEZZGKY-UHFFFAOYSA-N Copy
• CAS Registry Number: 557-20-0
• Chemical structure:
  This structure is also available as a 2d Mol file
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
  • Switch to SI units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Enthalpy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Enthalpy of fusion

Entropy of fusion

Entropy of fusion

Enthalpy of phase transition

Entropy of phase transition

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 (l) + ( • 100) (solution) = 2 (g) + ( • 100) (solution)

By formula: C₄H₁₀Zn (l) + (H₂O₄S • 100H₂O) (solution) = 2C₂H₆ (g) + (O₄SZn • 100H₂O) (solution)

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Lautsch, Erzberger, et al., 1958
Lautsch, W.F.; Erzberger, P.; Tröber, A., Wiss. Z. Tech. Hochsch. Chem. Leuna-Merseburg, 1958, 1, 31. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Long and Norrish, 1949
Long, L.H.; Norrish, R.G.W., Phil. Trans. Roy. Soc. (London), 1949, A241, 587. [all data]

Rabinovich, Nistratov, et al., 1988
Rabinovich, I.B.; Nistratov, V.P.; Fedoseev, V.B.; Sheiman, M.S.; Kamelova, G.P.; Karataev, E.N.; Feshchenko, I.A., Low-temperature specific heat and thermodynamic functions of diethylzinc, Zhur.Fiz. Khim., 1988, 62, 1349-1352. [all data]

Gibin, Grishnova, et al., 1987
Gibin, A.M.; Grishnova, N.D.; Gusev, A.V.; Moiseev, A.N.; Remeshkova, I.I.; Salganskii, Yu.M., Study of the heat capacity of high-purity diethyl zinc at 18-273 K, Vysokochist. Veshchestva, 1987, (6), 28-32. [all data]

Rabinovich, Nistratov, et al., 1988, 2
Rabinovich, I.B.; Nistratov, V.P.; Fedoseev, V.B.; Sheiman, M.S.; Kamelova, G.P.; Karataev, E.N., Low-temperature specific heat and thermodynamic functions of diethylzine, Zh. Fiz. Khim., 1988, 62, 1349. [all data]

Sokolovskii and Baev, 1984
Sokolovskii, A.E.; Baev, A.K., Zh. Obshch. Khim., 1984, 54, 103. [all data]

Bamford, Levi, et al., 1946
Bamford, C.H.; Levi, D.L.; Newitt, D.M., J. Chem. Soc., 1946, 468.. [all data]

House, 1983
House, J.E., Cohesion energies and solubility parameters for triethylboron and diethylzinc, Thermochimica Acta, 1983, 71, 1-2, 215-218, https://doi.org/10.1016/0040-6031(83)80370-0 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Gibin, Grishnova, et al., 1987, 2
Gibin, A.M.; Grishnova, N.D.; Gusev, A.V.; Moiseev, A.N.; Remeshkova, I.I.; Salganskii, Y.M., Vysokochist. Veshchestva, 1987, 28. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Carson, Hartley, et al., 1949
Carson, A.S.; Hartley, K.; Skinner, H.A., Thermochemistry of metal alkyls. Part II.?The bond dissociation energies of some Zn?C and Cd?C bonds, and of Et?I., Trans. Faraday Soc., 1949, 45, 1159, https://doi.org/10.1039/tf9494501159 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References

• Symbols used in this document:
  

  Cp,liquid	Constant pressure heat capacity of liquid
  S°liquid	Entropy of liquid at standard conditions
  Ttriple	Triple point temperature
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔcH°liquid	Enthalpy of combustion of liquid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔvapH	Enthalpy of vaporization
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.