NO2+


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

NO2+ + Nitrous oxide = (NO2+ • Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ • N2O)

Quantity Value Units Method Reference Comment
Δr14.1kcal/molEICameron, Aitken, et al., 1994gas phase
Δr17.4kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr13.1 ± 0.8kcal/molDTIllies, 1988gas phase; ΔrH(0 K)=13.3 kcal/mol
Δr13.1kcal/molPILinn and Ng, 1981gas phase
Quantity Value Units Method Reference Comment
Δr24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr12.4cal/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=13.3 kcal/mol

(NO2+ • 5Nitrous oxide) + Nitrous oxide = (NO2+ • 6Nitrous oxide)

By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)

Quantity Value Units Method Reference Comment
Δr3.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr22.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(NO2+ • 2Nitrous oxide) + Nitrous oxide = (NO2+ • 3Nitrous oxide)

By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)

Quantity Value Units Method Reference Comment
Δr2.8kcal/molEICameron, Aitken, et al., 1994gas phase
Δr5.6kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr24.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • Nitrous oxide) + Nitrous oxide = (NO2+ • 2Nitrous oxide)

By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)

Quantity Value Units Method Reference Comment
Δr5.1kcal/molEICameron, Aitken, et al., 1994gas phase
Δr5.7kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr18.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 10Nitrogen) + Nitrogen = (NO2+ • 11Nitrogen)

By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr1.5 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr18.6cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 11Nitrogen) + Nitrogen = (NO2+ • 12Nitrogen)

By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)

Quantity Value Units Method Reference Comment
Δr1.5 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr19.6cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 9Nitrogen) + Nitrogen = (NO2+ • 10Nitrogen)

By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr1.7 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr20.6cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 2Nitrogen) + Nitrogen = (NO2+ • 3Nitrogen)

By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr4.4 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr20.9cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 3Nitrogen) + Nitrogen = (NO2+ • 4Nitrogen)

By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr3.7 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr21.7cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 4Nitrogen) + Nitrogen = (NO2+ • 5Nitrogen)

By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr3.2 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr25.7cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 5Nitrogen) + Nitrogen = (NO2+ • 6Nitrogen)

By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr2.1 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr17.0cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 6Nitrogen) + Nitrogen = (NO2+ • 7Nitrogen)

By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr1.9 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr17.0cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 7Nitrogen) + Nitrogen = (NO2+ • 8Nitrogen)

By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr1.8 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr17.9cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 8Nitrogen) + Nitrogen = (NO2+ • 9Nitrogen)

By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr1.7 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr18.9cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • Nitrogen) + Nitrogen = (NO2+ • 2Nitrogen)

By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr4.5 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr19.7cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 3Nitrous oxide) + Nitrous oxide = (NO2+ • 4Nitrous oxide)

By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)

Quantity Value Units Method Reference Comment
Δr4.4kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 4Nitrous oxide) + Nitrous oxide = (NO2+ • 5Nitrous oxide)

By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)

Quantity Value Units Method Reference Comment
Δr4.1kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr22.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

NO2+ + Nitrogen = (NO2+ • Nitrogen)

By formula: NO2+ + N2 = (NO2+ • N2)

Quantity Value Units Method Reference Comment
Δr4.6 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr18.2cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

NO2+ + Water = (NO2+ • Water)

By formula: NO2+ + H2O = (NO2+ • H2O)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
16.1 (+2.3,-0.) PD/KERDGraul, Kim, et al., 1992gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W., Appearence Energies of Small Cluster Ions and their Fragments, J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935 . [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Linn and Ng, 1981
Linn, S.H.; Ng, C.Y., Photoionization Study of CO2, N2O Dimers and Clusters, J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931 . [all data]

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., How are Nitrogen Molecules Bound to NO2+ and NO+?, J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880 . [all data]

Graul, Kim, et al., 1992
Graul, S.T.; Kim, H.S.; Bowers, M.T., The Dynamics of Photodissociation of the Gas Phase (N2O.H2O)+ Cluster Ion, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 507, https://doi.org/10.1016/0168-1176(92)80111-D . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References