Methane, tetranitro-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas82. ± 2.kJ/molCcbLebedev, Miroshnichenko, et al., 1975 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid38. ± 2.kJ/molCcbLebedev, Miroshnichenko, et al., 1975 
Δfliquid37. ± 3.kJ/molCcbGardner and Grigger, 1963 
Δfliquid41.2 ± 4.2kJ/molCcbRoth and Isecke, 1944Reanalyzed by Cox and Pilcher, 1970, Original value = 37. ± 2. kJ/mol
Quantity Value Units Method Reference Comment
Δcliquid-432. ± 2.kJ/molCcbLebedev, Miroshnichenko, et al., 1975 
Δcliquid-434.7 ± 4.2kJ/molCcbRoth and Isecke, 1944Reanalyzed by Cox and Pilcher, 1970, Original value = -430.5 kJ/mol

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil399.2KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Tfus287.05KN/ATimmermans and Hennaut-Roland, 1955Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δvap49.96kJ/molN/AMajer and Svoboda, 1985 
Δvap43.9 ± 0.4kJ/molCLebedev, Miroshnichenko, et al., 1975ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
43.1301.AStephenson and Malanowski, 1987Based on data from 286. to 373. K.; AC
42.9328.AStephenson and Malanowski, 1987Based on data from 313. to 373. K. See also Boublik, Fried, et al., 1984 and Edwards, 1952.; AC
46.6288.N/AStephenson and Malanowski, 1987Based on data from 273. to 313. K. See also Boublik, Fried, et al., 1984 and Nicholson, 1949.; AC
40.74399.2N/AMajer and Svoboda, 1985 
43.1 ± 2.1313.VEdwards, 1952, 2Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 41. kJ/mol; ALS

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
313. to 373.4.549191582.071-49.74Edwards, 1952, 3Coefficents calculated by NIST from author's data.
273. to 313.1.75688498.772-158.538Nicholson, 1949, 2Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Reference Comment
47.4271.Stephenson and Malanowski, 1987Based on data from 255. to 286. K. See also Seki and Nitta, 1941.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Methane, tetranitro- + 6Carbon monoxide = 7Carbon dioxide + 2Nitrogen

By formula: CN4O8 + 6CO = 7CO2 + 2N2

Quantity Value Units Method Reference Comment
Δr-2128. ± 3.kJ/molCcbGardner and Grigger, 1963liquid phase

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin J.T.LARKINS U.S. DEPT. OF COMMERCE, WASHINGTON, D.C., USA
NIST MS number 38932

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedev, Miroshnichenko, et al., 1975
Lebedev, V.P.; Miroshnichenko, E.A.; Matyushin, Yu.N.; Larionov, V.P.; Romanov, V.S.; Bukolov, Yu.E.; Denisov, G.M.; Balepin, A.A.; Lebedev, Yu.A., Semimicrocalorimetric determination of gas-phase enthalpies of formation of compounds containing nitrogen and oxygen. II. calorimetric determinationi of enthalpies of formation [of Tetranitromethane], Russ. J. Phys. Chem. (Engl. Transl.), 1975, 49, 1133-1136, In original 1933. [all data]

Gardner and Grigger, 1963
Gardner, D.M.; Grigger, J.C., Heat of formation of tetranitromethane by combustion calorimetry, J. Chem. Eng. Data, 1963, 8, 73-74. [all data]

Roth and Isecke, 1944
Roth, W.A.; Isecke, K., Die verbrennungs- und bildungswarme des tetranitromethans, Ber., 1944, 77, 537-539. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Timmermans and Hennaut-Roland, 1955
Timmermans, J.; Hennaut-Roland, M., Work of the International Bureau of Physical-Chemical Standards. IX. The Physical Constants of Twenty Organic Compounds, J. Chim. Phys. Phys.-Chim. Biol., 1955, 52, 223. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Edwards, 1952
Edwards, G., The vapour pressure of tetranitromethane, Trans. Faraday Soc., 1952, 48, 513, https://doi.org/10.1039/tf9524800513 . [all data]

Nicholson, 1949
Nicholson, A.J.C., 331. Some physical properties of tetranitromethane, J. Chem. Soc., 1949, 1553, https://doi.org/10.1039/jr9490001553 . [all data]

Edwards, 1952, 2
Edwards, G., The vapour pressure of tetranitromethane, Trans. Faraday Soc., 1952, 48, 000. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Edwards, 1952, 3
Edwards, G., The Vapour Pressure of Tetranitromethane, Trans. Faraday Soc., 1952, 48, 513-515, https://doi.org/10.1039/tf9524800513 . [all data]

Nicholson, 1949, 2
Nicholson, A.J.C., Some Physical Properties of Tetranitromethane, J. Chem. Soc., 1949, 1553-1555, https://doi.org/10.1039/jr9490001553 . [all data]

Seki and Nitta, 1941
Seki, S.; Nitta, I., J. Chem. Soc. Jpn., 1941, 62, 907. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References