2-Amino-2-methyl-1,3-propanediol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus384.KN/AMurrill and Breed, 1970Crystal phase 1 phase; Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Ttriple384.08KN/AZhang and Yang, 1990Crystal phase 1 phase; Uncertainty assigned by TRC = 0.05 K; TRC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
424.70.013Weast and Grasselli, 1989BS

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
0.660384.1DSCDivi, Chellappa, et al., 2006AC
0.715384.N/ADomalski and Hearing, 1996See also López, Van Braak, et al., 1994.; AC
0.664384.1ACZhang and Yang, 1990, 2Based on data from 283. to 393. K.; AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
17.12352.Domalski and Hearing, 1996CAL
1.86384.

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
16.79351.3Donnelly, Drewes, et al., 1990CAL
1.70383.6

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
3.387352.9Zhang and Yang, 1990CAL
12.47353.7
1.73384.1

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
6.0241352.crystaline, IIcrystaline, IMurrill and Breed, 1970, 2DH
0.7149384.crystaline, IliquidMurrill and Breed, 1970, 2DH
5.8987351.25crystaline, IIcrystaline, IBarrio, Font, et al., 1991DH
0.6527383.55crystaline, IliquidBarrio, Font, et al., 1991DH
5.8987351.25crystaline, IIcrystaline, IBarrio, Font, et al., 1991DH
0.6527383.55crystaline, IliquidBarrio, Font, et al., 1991DH
1.195352.89crystaline, IIIcrystaline, IIZhang and Yang, 1990, 2DH
4.4120353.72crystaline, IIcrystaline, IZhang and Yang, 1990, 2DH
0.6644384.08crystaline, IliquidZhang and Yang, 1990, 2DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
17.2352.crystaline, IIcrystaline, IMurrill and Breed, 1970, 2DH
1.9384.crystaline, IliquidMurrill and Breed, 1970, 2DH
3.39352.89crystaline, IIIcrystaline, IIZhang and Yang, 1990, 2DH
12.5353.72crystaline, IIcrystaline, IZhang and Yang, 1990, 2DH
1.73384.08crystaline, IliquidZhang and Yang, 1990, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murrill and Breed, 1970
Murrill, E.; Breed, L.W., Solid-solid phase transitions determined by differential scanning calorime- try. Part I. Tetrahedral Substances., Thermochim. Acta, 1970, 1, 239. [all data]

Zhang and Yang, 1990
Zhang, Z.; Yang, M.L., Heat capacity and phase transition of 2-amino-2-methyl-1,3-propanediol from 280 K to the melting point, Thermochim. Acta, 1990, 169, 263, https://doi.org/10.1016/0040-6031(90)80153-P . [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Divi, Chellappa, et al., 2006
Divi, Suresh; Chellappa, Raja; Chandra, Dhanesh, Heat capacity measurement of organic thermal energy storage materials, The Journal of Chemical Thermodynamics, 2006, 38, 11, 1312-1326, https://doi.org/10.1016/j.jct.2006.02.005 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

López, Van Braak, et al., 1994
López, D.O.; Van Braak, J.; Tamarit, J.L.L.; Oonk, H.A.J., Thermodynamic phase diagram analysis of three binary systems shared by five neopentane derivatives, Calphad, 1994, 18, 4, 387-396, https://doi.org/10.1016/0364-5916(94)90016-7 . [all data]

Zhang and Yang, 1990, 2
Zhang, Z.Y.; Yang, M.L., Heat capactiy and phase transition of 2-amino-2-methyl-1,3-propanediol from 280K to the melting point, Thermochim. Acta, 1990, 169, 263-269. [all data]

Donnelly, Drewes, et al., 1990
Donnelly, J.R.; Drewes, L.A.; Johnson, R.L.; Munslow, W.D.; Knapp, K.K.; Sovocool, G.W., Purity and heat of fusion data for environmental standards as determined by differential scanning calorimetry, Thermochim. Acta, 1990, 167, 2, 155, https://doi.org/10.1016/0040-6031(90)80476-F . [all data]

Murrill and Breed, 1970, 2
Murrill, E.; Breed, L., Solid-solid phase transitions determined by differential scanning calorimetry, Thermochim. Acta, 1970, 1, 239-246. [all data]

Barrio, Font, et al., 1991
Barrio, M.; Font, J.; Lopez, D.O.; Muntasell, J.; Tamarit, J.L., Polymorphism in the 2-amino-2-methyl-1,3-propanediol plastic crystal, Calorim. Anal. Therm., 1991, 22, 291-297. [all data]


Notes

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