Butane, 2-methoxy-2-methyl-
- Formula: C6H14O
- Molecular weight: 102.1748
- IUPAC Standard InChIKey: HVZJRWJGKQPSFL-UHFFFAOYSA-N
- CAS Registry Number: 994-05-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ether, methyl tert-pentyl; tert-Amyl Methyl ether; Methyl tert-pentyl ether; 1,1-Dimethylpropyl methyl ether; 2-Methyl-2-methoxybutane; Methyl 2-methyl-2-butyl ether; 2-Methoxy-2-methylbutane
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C5H10 + CH4O = C6H14O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -8.56 | kcal/mol | Eqk | Serda, Izquierdo, et al., 1995 | liquid phase |
ΔrH° | -4.9 ± 0.2 | kcal/mol | Eqk | Hwang and Wu, 1994 | liquid phase |
ΔrH° | -8.0 ± 1.2 | kcal/mol | Eqk | Rihko, Linnekoski, et al., 1994 | liquid phase; solvent: Alcohol/alkane mixture |
By formula: C5H10 + CH4O = C6H14O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -7.84 | kcal/mol | Eqk | Serda, Izquierdo, et al., 1995 | liquid phase |
ΔrH° | -6.41 ± 0.55 | kcal/mol | Eqk | Rihko, Linnekoski, et al., 1994 | liquid phase; solvent: Alcohol/alkane mixture |
By formula: C6H14O = C5H10 + CH4O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16.24 ± 0.093 | kcal/mol | Eqk | Rozhnov, Safronov, et al., 1991 | liquid phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Serda, Izquierdo, et al., 1995
Serda, J.A.; Izquierdo, J.F.; Tejero, J.; Cunill, F.; Iborra, M.,
Equilibrium and thermodynamics for 2-methyl-2-methoxybutane liquid-phase decomposition,
Thermochim. Acta, 1995, 259, 111-120. [all data]
Hwang and Wu, 1994
Hwang, W.-S.; Wu, J.-C.,
Kinetics and thermodynamics of synthesis of tertiary-amyl methyl ether catalyzed by ion-exchange resin,
J. Chin. Chem. Soc. (Taipei), 1994, 41, 181-186. [all data]
Rihko, Linnekoski, et al., 1994
Rihko, L.K.; Linnekoski, J.A.; Krause, A.O.,
Reaction equilibria in the synthesis of 2-methoxy-2-methylbutane and 2-ethyoxy-2-methylbutane in the liquid phase,
J. Chem. Eng. Data, 1994, 39, 700-704. [all data]
Rozhnov, Safronov, et al., 1991
Rozhnov, A.M.; Safronov, V.V.; Verevkin, S.P.; Sharonov, K.G.; Alenin, V.I.,
Enthalpy of combustion and enthalpy of vaporization of 2-ethyl-2-methoxypropane and thermodynamics of its gas-phase synthesis from (methanol + a 2-methylbutene),
J. Chem. Thermodyn., 1991, 23, 629-635. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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