β-D-Glucopyranose, 4-O-β-D-galactopyranosyl-
- Formula: C12H22O11
- Molecular weight: 342.2965
- IUPAC Standard InChIKey: GUBGYTABKSRVRQ-OXMKDSILSA-N
- CAS Registry Number: 5965-66-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: Lactose, β-; β-Lactose; 4-O-β-D-Galactopyranosyl-β-D-glucopyranose; beta-Lactose; β-D-Lactose; Lactopress
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -534.59 ± 0.17 | kcal/mol | Ccb | Clarke and Stegeman, 1939 | Reanalyzed by Cox and Pilcher, 1970, Original value = -534.38 kcal/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -1345.47 ± 0.12 | kcal/mol | Ccb | Clarke and Stegeman, 1939 | Corresponding ΔfHºsolid = -534.61 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 92.30 | cal/mol*K | N/A | Anderson and Stegeman, 1941 | Extrapolation below 90 K, 94.6 J/mol*K.; DH |
S°solid,1 bar | 96.39 | cal/mol*K | N/A | Furtsch and Stegeman, 1936 | Extrapolation below 90 K, 26.00 cal/mol*K.; DH |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
95.550 | 289.44 | Anderson and Stegeman, 1941 | T = 65 to 290 K. Value is unsmoothed experimental datum.; DH |
97.579 | 298.44 | Furtsch and Stegeman, 1936 | T = 83 to 298 K. Value is unsmoothed experimental datum.; DH |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: C12H22O11 + H2O = C6H12O6 + C6H12O6
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 0.11 ± 0.026 | kcal/mol | Eqk | Goldberg and Tewari, 1989 | liquid phase; solvent: Aqueous; HPLC |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | COBLENTZ SOCIETY Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | WYANDOTTE CHEMICALS CORP., WYANDOTTE, MICHIGAN, USA |
Source reference | COBLENTZ NO. 2831 |
Date | Not specified, most likely prior to 1970 |
Name(s) | 4-O-hexopyranosylhexopyranose |
State | SOLID (MINERAL OIL MULL) |
Instrument | Not specified, most likely a prism, grating, or hybrid spectrometer. |
Path length | SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900 CM-1 |
Resolution | 4 |
Sampling procedure | TRANSMISSION |
Data processing | DIGITIZED BY NIST FROM HARD COPY |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-IW-4088 |
NIST MS number | 236508 |
References
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Clarke and Stegeman, 1939
Clarke, T.H.; Stegeman, G.,
Heats of combustion of some mono- and disaccharides,
J. Am. Chem. Soc., 1939, 61, 1726-1730. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Anderson and Stegeman, 1941
Anderson, A.G.; Stegeman, G.,
The heat capacities and entropies of three disacchardes,
J. Am. Chem. Soc., 1941, 63, 2119-2121. [all data]
Furtsch and Stegeman, 1936
Furtsch, E.F.; Stegeman, G.,
The heat capacity and entropy of b-lactose,
J. Am. Chem. Soc., 1936, 58, 881-882. [all data]
Goldberg and Tewari, 1989
Goldberg, R.N.; Tewari, Y.B.,
A calorimetric and equilibrium investigatino of the hydrolysis of lactose,
J. Biol. Chem., 1989, 264, 9897-9900. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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