β-D-Glucopyranose, 4-O-β-D-galactopyranosyl-


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-534.59 ± 0.17kcal/molCcbClarke and Stegeman, 1939Reanalyzed by Cox and Pilcher, 1970, Original value = -534.38 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Δcsolid-1345.47 ± 0.12kcal/molCcbClarke and Stegeman, 1939Corresponding Δfsolid = -534.61 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar92.30cal/mol*KN/AAnderson and Stegeman, 1941Extrapolation below 90 K, 94.6 J/mol*K.; DH
solid,1 bar96.39cal/mol*KN/AFurtsch and Stegeman, 1936Extrapolation below 90 K, 26.00 cal/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
95.550289.44Anderson and Stegeman, 1941T = 65 to 290 K. Value is unsmoothed experimental datum.; DH
97.579298.44Furtsch and Stegeman, 1936T = 83 to 298 K. Value is unsmoothed experimental datum.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

β-D-Glucopyranose, 4-O-β-D-galactopyranosyl- + Water = α-D-Glucopyranose + α-d-Galactopyranose

By formula: C12H22O11 + H2O = C6H12O6 + C6H12O6

Quantity Value Units Method Reference Comment
Δr0.11 ± 0.026kcal/molEqkGoldberg and Tewari, 1989liquid phase; solvent: Aqueous; HPLC

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin WYANDOTTE CHEMICALS CORP., WYANDOTTE, MICHIGAN, USA
Source reference COBLENTZ NO. 2831
Date Not specified, most likely prior to 1970
Name(s) 4-O-hexopyranosylhexopyranose
State SOLID (MINERAL OIL MULL)
Instrument Not specified, most likely a prism, grating, or hybrid spectrometer.
Path length
SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900 CM-1
Resolution 4
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY NIST FROM HARD COPY

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW-4088
NIST MS number 236508

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clarke and Stegeman, 1939
Clarke, T.H.; Stegeman, G., Heats of combustion of some mono- and disaccharides, J. Am. Chem. Soc., 1939, 61, 1726-1730. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Anderson and Stegeman, 1941
Anderson, A.G.; Stegeman, G., The heat capacities and entropies of three disacchardes, J. Am. Chem. Soc., 1941, 63, 2119-2121. [all data]

Furtsch and Stegeman, 1936
Furtsch, E.F.; Stegeman, G., The heat capacity and entropy of b-lactose, J. Am. Chem. Soc., 1936, 58, 881-882. [all data]

Goldberg and Tewari, 1989
Goldberg, R.N.; Tewari, Y.B., A calorimetric and equilibrium investigatino of the hydrolysis of lactose, J. Biol. Chem., 1989, 264, 9897-9900. [all data]


Notes

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