(CS2)2 radical anion
- Formula: C2S4-
- Molecular weight: 152.282
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.65001 | LPES | Mabbs, Surber, et al., 2003 | Vertical Detachment Energy. From CS2 solvated CS2-. See also Maeyama, Oikawa, et al., 1998. See Matsuyama and Nagata, 2008 for exptl. structure |
| 2.69998 | LPES | Mabbs, Surber, et al., 2003 | Vertical Detachment Energy. From covalent bound dimer anion |
| 1.650 ± 0.020 | LPES | Tsukuda, Hirose, et al., 1997 | EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mabbs, Surber, et al., 2003
Mabbs, R.; Surber, E.; Sanov, A.,
An experimental manifestation of distinct electronic-structural properties of covalent dimer anions of CO2 and CS2,
Chem. Phys., 2003, 381, 479-485. [all data]
Maeyama, Oikawa, et al., 1998
Maeyama, T.; Oikawa, T.; Tsumura, T.; Mikami, N.,
Photodestruction spectroscopy of carbon disulfide cluster anions (CS2)(n)(-) n=1-4: Evidence for the dimer core structure and competitive reactions of the dimer anion,
J. Chem. Phys., 1998, 108, 4, 1368-1376, https://doi.org/10.1063/1.475510
. [all data]
Matsuyama and Nagata, 2008
Matsuyama, Y.; Nagata, T.,
Structures of C2S4- Molecular Anion: Photoelectron Spectroscopy and Theoretical Calculations,
Chem. Phys. Lett., 2008, 457, 1-3, 31-35., https://doi.org/10.1016/j.cplett.2008.03.068
. [all data]
Tsukuda, Hirose, et al., 1997
Tsukuda, T.; Hirose, T.; Nagata, T.,
Negative-ion photoelectron spectroscopy of (CS2)(n)(-): coexistence of electronic isomers,
Chem. Phys. Lett., 1997, 279, 3-4, 179-184, https://doi.org/10.1016/S0009-2614(97)01021-X
. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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