d-Mannose
- Formula: C6H12O6
- Molecular weight: 180.1559
- IUPAC Standard InChIKey: GZCGUPFRVQAUEE-KVTDHHQDSA-N
- CAS Registry Number: 3458-28-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Other names: Mannose, d-; Carubinose; d(+)-Mannose; Mannose; Seminose
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- Comments:
- Although only a single structure is shown, this species may exist in several forms including a linear molecule and a six membered ring.
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Condensed phase thermochemistry data
Go To: Top, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -301.95 ± 0.30 | kcal/mol | Ccb | Wu, Finch, et al., 1987 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -672.24 ± 0.22 | kcal/mol | Ccb | Wu, Finch, et al., 1987 | Corresponding ΔfHºsolid = -301.953 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°solid | -672.33 ± 0.81 | kcal/mol | Ccb | Stroh and Fincke, 1963 | Corresponding ΔfHºsolid = -301.87 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
Constant pressure heat capacity of solid
Cp,solid (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
51.6 | 303. | Kawaizumi, Kushida, et al., 1981 | T = 300 to 315 K.; DH |
51.20 | 300. | Kawaizumi, Nishio, et al., 1981 | T = 270 to 325 K. Cp given as 1.19 J/g*K.; DH |
IR Spectrum
Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Condensed Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
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Owner | COBLENTZ SOCIETY Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | WYANDOTTE CHEMICALS CORP., WYANDOTTE, MICHIGAN, USA |
Source reference | COBLENTZ NO. 2855 |
Date | Not specified, most likely prior to 1970 |
Name(s) | hexopyranose |
State | SOLID (MINERAL OIL MULL) |
Instrument | Not specified, most likely a prism, grating, or hybrid spectrometer. |
Path length | SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900 CM-1 |
Resolution | 4 |
Sampling procedure | TRANSMISSION |
Data processing | DIGITIZED BY NIST FROM HARD COPY |
Melting point | 128.5 C |
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | RADIAN CORP |
NIST MS number | 76401 |
References
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wu, Finch, et al., 1987
Wu, D.; Finch, A.; Gardner, P.J.,
Standard energy of combustion and enthalpy of formation of α-D-mannose,
Wuhan Daxue Zuebao, Ziran Kexueban, 1987, 59-63. [all data]
Stroh and Fincke, 1963
Stroh, H.H.; Fincke, C.R.,
Beobachtung ciner unterschidlichen hydrierbarkeit von n-substituiertten aziridin-derivaten,
Z. Chem., 1963, 3, 265-266. [all data]
Kawaizumi, Kushida, et al., 1981
Kawaizumi, F.; Kushida, S.; Miyahara, Y.,
Determination of the specific heat capacities of aqueous solutions of pentose,
Bull. Chem. Soc. Japan, 1981, 54(8), 2282-2285. [all data]
Kawaizumi, Nishio, et al., 1981
Kawaizumi, F.; Nishio, N.; Nomura, H.; Miyahara, Y.,
Heat-capacity measurements of aqueous solutions of mono-, di-, and tri-saccharides using an isoperibol twin calorimeter,
J. Chem. Thermodynam., 1981, 13, 89-98. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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