Osmium, dodecacarbonyltri-, triangulo
- Formula: C12O12Os3
- Molecular weight: 906.81
- IUPAC Standard InChIKey: VUBLMKVEIPBYME-UHFFFAOYSA-N
- CAS Registry Number: 15696-40-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Dodecacarbonyl-triangulo-triosmium; Dodecacarbonyltriosmium; Osmium carbonyl (Os3(CO)12); Osmium dodecacarbonyl; Triosmium dodecacarbonyl; Os3(CO)12; Osmium carbonyl; Triangulo-dodecacarbonyltriosmium
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -1644. ± 26. | kJ/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -1749. ± 17. | kJ/mol | Review | Martinho Simões |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 105. ± 20. | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Connor, Skinner, et al., 1973.; AC |
ΔsubH° | 105. ± 20. | kJ/mol | TD-HFC | Connor, Skinner, et al., 1973 | MS |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
101.7 | 520. | Gaidym, Baev, et al., 1974 | Based on data from 497. to 543. K.; AC |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
134.4 ± 0.4 | 349. to 396. | Chandra, Garner, et al., 1999 | AC |
108.4 | 483. | Gaidym, Baev, et al., 1974, 2 | Based on data from 423. to 543. K.; AC |
Mass spectrum (electron ionization)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | B.F.G.JOHNSON DEPT. OF CHEM., UNIV. OF MANCHESTER, UK |
NIST MS number | 18778 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y.,
High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir,
Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018
. [all data]
Gaidym, Baev, et al., 1974
Gaidym, I.L.; Baev, A.K.; Syrkin, V.G.; Uel'skii, A.A.; Medvedeva, A.E.,
Russ. J. Phys. Chem., 1974, 48, 1111. [all data]
Chandra, Garner, et al., 1999
Chandra, D.; Garner, M.L.; Lau, K.H.,
Vapor pressures of osmium, rhodium, and ruthenium carbonyls,
JPE, 1999, 20, 6, 565-572, https://doi.org/10.1361/105497199770340554
. [all data]
Gaidym, Baev, et al., 1974, 2
Gaidym, I.L.; Baev, A.K.; Syrkin, V.G.; Uel'skii, A.A.; Medvedeva, A.V.,
Zh. Fiz. Khim., 1974, 48, 1871. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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