1,3-Diethoxypropane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-436.2 ± 1.5kJ/molCcrMansson, 1972 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-482.1 ± 1.5kJ/molCcrMansson, 1972 
Quantity Value Units Method Reference Comment
Δcliquid-4559.1 ± 1.4kJ/molCcrMansson, 1972Corresponding Δfliquid = -482.1 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil413.7KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Δvap45.92kJ/molN/AMajer and Svoboda, 1985 
Δvap45.9 ± 0.2kJ/molCMånsson, Hurum, et al., 1972AC
Δvap45.9 ± 0.2kJ/molCMansson, 1972ALS
Δvap45.9kJ/molN/AMansson, 1972DRB

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
37.17413.7Majer and Svoboda, 1985 

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
PackedApiezon L828.2Keiko, Prokop'ev, et al., 1972Program: not specified
PackedSqualane836.5Keiko, Prokop'ev, et al., 1972Program: not specified

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mansson, 1972
Mansson, M., Non-bonded oxygen-oxygen interactions. 3,7-Dioxanonane, Acta Chem. Scand., 1972, 26, 1707-1708. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Månsson, Hurum, et al., 1972
Månsson, Margret; Hurum, Torgeir; Dale, Johannes; Øye, H.A.; Svensson, Sigfrid, Non-bonded Oxygen-Oxygen Interactions. 3,7-Dioxanonane., Acta Chem. Scand., 1972, 26, 1707-1708, https://doi.org/10.3891/acta.chem.scand.26-1707 . [all data]

Keiko, Prokop'ev, et al., 1972
Keiko, V.V.; Prokop'ev, B.V.; Kuz'menko, L.P.; Kalinina, N.A.; Modonov, V.B., The use of an additive scheme of calculation of the indices of retention in gas-liquid chromatography communication. 3. Some regularities in the manifestation of the inductive effect, Izv. Akad. Nauk Kaz. SSR Ser. Khim., 1972, 12, 2629-2633. [all data]


Notes

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