Ozone anion
- Formula: O3-
- Molecular weight: 47.9987
- CAS Registry Number: 12596-80-4
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Gas phase thermochemistry data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -14.610 ± 0.060 | kcal/mol | R-EA | Novich, Engelking, et al., 1979 |
Ion clustering data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
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Clustering reactions
By formula: (O3- • H2O) + H2O = (O3- • 2H2O)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
6.2 | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; M |
By formula: (O3- • 2H2O) + H2O = (O3- • 3H2O)
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
4.5 | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; M |
By formula: O3- + N2 = (O3- • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.70 ± 0.20 | kcal/mol | TDAs | Hiraoka, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.4 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -2.80 ± 0.50 | kcal/mol | TDAs | Hiraoka, 1988 | gas phase; B |
By formula: (O3- • N2) + N2 = (O3- • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.6 ± 0.2 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.6 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 2N2) + N2 = (O3- • 3N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.5 ± 0.2 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.7 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 3N2) + N2 = (O3- • 4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.3 ± 0.2 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.2 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 4N2) + N2 = (O3- • 5N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.1 ± 0.2 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.7 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 5N2) + N2 = (O3- • 6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.0 ± 0.2 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.0 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 6N2) + N2 = (O3- • 7N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.8 ± 0.2 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.2 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 7N2) + N2 = (O3- • 8N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.7 ± 0.3 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.5 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 8N2) + N2 = (O3- • 9N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.5 ± 0.4 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.9 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: O3- + O2 = (O3- • O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.10 ± 0.20 | kcal/mol | TDAs | Hiraoka, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.0 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -3.60 ± 0.50 | kcal/mol | TDAs | Hiraoka, 1988 | gas phase; B |
By formula: (O3- • O2) + O2 = (O3- • 2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.0 ± 0.2 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.4 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 2O2) + O2 = (O3- • 3O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.0 ± 0.3 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.0 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 3O2) + O2 = (O3- • 4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.6 ± 0.3 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 15.4 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 4O2) + O2 = (O3- • 5O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.54 | kcal/mol | PHPMS | Hiraoka, 1988 | gas phase; ΔrH, ΔrS approximate; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.4 | cal/mol*K | PHPMS | Hiraoka, 1988 | gas phase; ΔrH, ΔrS approximate; M |
References
Go To: Top, Gas phase thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C.,
Laser photoelectron, photodetachment, and photodestruction spectra of O3-,
J. Chem. Phys., 1979, 70, 2652. [all data]
Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E.,
Laboratory studies of negative ion reactions with atmospheric trace constituents,
J. Chem. Phys., 1974, 61, 3181. [all data]
Hiraoka, 1988
Hiraoka, K.,
Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria,
Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Ion clustering data, References
- Symbols used in this document:
T Temperature ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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