sodium formate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
solid,1 bar24.799cal/mol*KN/AFranzosini, Plautz, et al., 1983S data taken from 60WES/CHA.
solid,1 bar24.799cal/mol*KN/AWestrum, Chang, et al., 1960 

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
20.96298.15Franzosini, Plautz, et al., 1983T = 300 to 520 K. Cp data taken from Westrum, Chang, et al., 1960 in temperature range 5 to 350 K.
21.1340.Ferloni, Sanesi, et al., 1975T = 340 to 560 K.
20.96298.15Westrum, Chang, et al., 1960T = 5 to 350 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple530.46KN/AFranzosini, Plautz, et al., 1983, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.2902491.5crystaline, IIcrystaline, IFranzosini, Plautz, et al., 1983DH
4.2328530.46crystaline, IliquidFranzosini, Plautz, et al., 1983DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.590491.5crystaline, IIcrystaline, IFranzosini, Plautz, et al., 1983DH
7.980530.46crystaline, IliquidFranzosini, Plautz, et al., 1983DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Franzosini, Plautz, et al., 1983
Franzosini, P.; Plautz, W.A.; Westrum, E.F., Jr., Thermophysics of metal alkanoates. I. Heat capacities and thermodynamic properties of sodium methanoate and ethanoate, J. Chem. Thermodynam., 1983, 15, 445-456. [all data]

Westrum, Chang, et al., 1960
Westrum, E.F., Jr.; Chang, S-S.; Levitin, N.E., The heat capacity and thermodynamic properties of sodium formate from 5 to 350K, J. Phys. Chem., 1960, 64, 1553-1554. [all data]

Ferloni, Sanesi, et al., 1975
Ferloni, P.; Sanesi, M.; Franzosini, P.; C4 alkanoates, Phase transitions in the alkali C1-n., Z. Naturforsch. 30a, 1975, 1447-1454. [all data]

Franzosini, Plautz, et al., 1983, 2
Franzosini, P.; Plautz, W.A.; Westrum, E.F., Thermophysics of metal alkanoates. I. Heat capacities and thermodynamic properties of sodium methanoate and ethanoate, J. Chem. Thermodyn., 1983, 15, 445. [all data]


Notes

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