Butane, 1,1'-sulfonylbis-
- Formula: C8H18O2S
- Molecular weight: 178.292
- IUPAC Standard InChI: InChI=1S/C8H18O2S/c1-3-5-7-11(9,10)8-6-4-2/h3-8H2,1-2H3
- IUPAC Standard InChIKey: AIDFJGKWTOULTC-UHFFFAOYSA-N
- CAS Registry Number: 598-04-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Butyl sulfone; Dibutyl sulfone; Dibutyl sulphone; 1,1'-Sulphonylbisbutane; Di-n-butyl sulfone; n-Butyl sulfone; 1-(Butylsulfonyl)butane; NSC 2116
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -509.8 ± 3.2 | kJ/mol | Ccb | Mackle and O'Hare, 1961 | Reanalyzed by Cox and Pilcher, 1970, Original value = -508. ± 3. kJ/mol; Hfusion=2.7±0.3 kcal/mol,Heat of comb. corrected for constant pressure |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -610.2 ± 2.0 | kJ/mol | Ccb | Mackle and O'Hare, 1961 | Reanalyzed by Cox and Pilcher, 1970, Original value = -609. ± 2. kJ/mol; Hfusion=2.7±0.3 kcal/mol,Heat of comb. corrected for constant pressure |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -5712.7 ± 1.9 | kJ/mol | Ccb | Mackle and O'Hare, 1961 | Reanalyzed by Cox and Pilcher, 1970, Original value = -5713.80 ± 0.59 kJ/mol; Hfusion=2.7±0.3 kcal/mol,Heat of comb. corrected for constant pressure |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tfus | 317. ± 1. | K | AVG | N/A | Average of 9 values; Individual data points |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔsubH° | 100. ± 2. | kJ/mol | V | Mackle and O'Hare, 1961 | Hfusion=2.7±0.3 kcal/mol,Heat of comb. corrected for constant pressure; ALS |
IR Spectrum
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compiled by: Coblentz Society, Inc.
- SOLID (MINERAL OIL MULL); Not specified, most likely a prism, grating, or hybrid spectrometer.; DIGITIZED BY NIST FROM HARD COPY; 4 cm-1 resolution
- SOLUTION (10% CCl4 FOR 3800-1340, 10% CS2 FOR 1340-450 CM-1); DOW KBr FOREPRISM-GRATING; DIGITIZED BY COBLENTZ SOCIETY (BATCH I) FROM HARD COPY; 2 cm-1 resolution
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G.,
Studies in the thermochemistry of sulphones. Part 5.-Heats of combustion, formation, fusion, vaporization and atomization of eleven aliphatic sulphones,
Trans. Faraday Soc., 1961, 57, 1070-1074. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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