1,1,1-Trichloro-3,3,3-trifluoropropane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-198.53 ± 0.22kcal/molCcrKolesov, Tomareva, et al., 1968HF(1:600 H2O) and HCl(1:600 H2O);hf298_gas[kcal/mol]=-192.14±0.53; Kolesov and Kozina, 1986
Quantity Value Units Method Reference Comment
Δcliquid-295.01 ± 0.22kcal/molCcrKolesov, Tomareva, et al., 1968HF(1:600 H2O) and HCl(1:600 H2O);hf298_gas[kcal/mol]=-192.14±0.53; Kolesov and Kozina, 1986

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Ttriple232.69KN/AKolesov and Vorob'ev, 1971Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Δvap8.80 ± 0.02kcal/molCVarushchenko, Druzhinina, et al., 2007AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
8.41335.Stephenson and Malanowski, 1987Based on data from 320. to 365. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
3.363232.7Acree, 1991AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kolesov, Tomareva, et al., 1968
Kolesov, V.P.; Tomareva, E.M.; Skuratov, S.M., Standard enthalpies of formation of 1,1,1-Trifluoro-3-chloropropane and 1,1,1-trifluoro-3,3,3-trichloropropane, Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1968, 23, 18-20, In original 30. [all data]

Kolesov and Kozina, 1986
Kolesov, V.P.; Kozina, M.P., Thermochemistry of organic and organohalogen compounds, Russ. Chem. Rev., 1986, 55, 912. [all data]

Kolesov and Vorob'ev, 1971
Kolesov, V.P.; Vorob'ev, V.N., Heat Capacity at 12 - 300 K and Thermodynamic Functions of 1,1,1-Trichloro- 3,3,3-trifluoropropane, Zh. Fiz. Khim., 1971, 45, 1293-4. [all data]

Varushchenko, Druzhinina, et al., 2007
Varushchenko, R.M.; Druzhinina, A.I.; Kuramshina, G.M.; Dorofeeva, O.V., Thermodynamics of vaporization of some freons and halogenated ethanes and propanes, Fluid Phase Equilibria, 2007, 256, 1-2, 112-122, https://doi.org/10.1016/j.fluid.2007.02.017 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Acree, 1991
Acree, William E., Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation, Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H . [all data]


Notes

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