CHN2


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CN2- + Hydrogen cation = CHN2

By formula: CN2- + H+ = CHN2

Quantity Value Units Method Reference Comment
Δr352.0 ± 4.3kcal/molG+TSClifford, Wenthold, et al., 1998gas phase; between pyrazole, tBuSH
Quantity Value Units Method Reference Comment
Δr344.3 ± 4.0kcal/molIMRBClifford, Wenthold, et al., 1998gas phase; between pyrazole, tBuSH

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to CHN2+ (ion structure unspecified)

De-protonation reactions

CN2- + Hydrogen cation = CHN2

By formula: CN2- + H+ = CHN2

Quantity Value Units Method Reference Comment
Δr352.0 ± 4.3kcal/molG+TSClifford, Wenthold, et al., 1998gas phase; between pyrazole, tBuSH
Quantity Value Units Method Reference Comment
Δr344.3 ± 4.0kcal/molIMRBClifford, Wenthold, et al., 1998gas phase; between pyrazole, tBuSH

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clifford, Wenthold, et al., 1998
Clifford, E.P.; Wenthold, P.G.; Lineberger, W.C.; Peterssom, G.A.; Broaddus, K.M.; Kass, S.R.; Kato, S., Properties of Diazocarbene [CNN] and the diazomethyl Radical [HCNN] via Ion Chemistry and Spectroscopy, J. Phys. Chem. A, 1998, 102, 36, 7100, https://doi.org/10.1021/jp9802735 . [all data]


Notes

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