Methyl nitrite

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-15.64 ± 0.20kcal/molEqkRay and Gershon, 1962 
Δfgas-16.8 ± 0.8kcal/molCcbGeiseler and Thierfelder, 1961 
Δfgas-14.93 ± 0.26kcal/molCmGray and Pratt, 1958Measured by Baldrey, Lotzgesell and Style
Quantity Value Units Method Reference Comment
Δcgas-179.7 ± 0.8kcal/molCcbGeiseler and Thierfelder, 1961 

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-101268.Zenkevich, 200525. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ray and Gershon, 1962
Ray, J.D.; Gershon, A.A., The heat of formation of gaseous methyl nitrite, J. Phys. Chem., 1962, 66, 1750-1752. [all data]

Geiseler and Thierfelder, 1961
Geiseler, G.; Thierfelder, W., Bestimmung der bildungswarme des gasformigen methylnitrits, Z. Phys. Chem. (Neue Folge), 1961, 29, 248-257. [all data]

Gray and Pratt, 1958
Gray, P.; Pratt, M.W.T., 687. The thermodynamic functions of methyl nitrite and the potential barrier to free rotation., J. Chem. Soc., 1958, 3403-3412. [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]


Notes

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