PhCH2OH..F anion
- Formula: C7H8FO-
- Molecular weight: 127.1368
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -115.87 | kcal/mol | Ther | Mihalick, Gatev, et al., 1996 | affinity derived using a ROH..F. neutral binding energy of 10.3 kcal/mol. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 3.040 ± 0.022 | LPD | Mihalick, Gatev, et al., 1996 | affinity derived using a ROH..F. neutral binding energy of 10.3 kcal/mol. |
| <3.050 ± 0.060 | PD | Moylan, Dodd, et al., 1987 |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mihalick, Gatev, et al., 1996
Mihalick, J.E.; Gatev, G.G.; Brauman, J.I.,
Electron Photodetachment Spectroscopy of Solvated Anions: RO.HF- or ROH.F-?,
J. Am. Chem. Soc., 1996, 118, 49, 12424, https://doi.org/10.1021/ja954202k
. [all data]
Moylan, Dodd, et al., 1987
Moylan, C.R.; Dodd, J.A.; Han, C.-C.; Brauman, J.I.,
Spectroscopy of Reactive Intermediates: Electron Photodetachment from Solvated Anions,
J. Chem. Phys., 1987, 86, 10, 5350, https://doi.org/10.1063/1.452560
. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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