CH4Si
- Formula: CH4Si
- Molecular weight: 44.1280
- CAS Registry Number: 51067-84-6
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Reaction thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
CH3Si- + = CH4Si
By formula: CH3Si- + H+ = CH4Si
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 364.2 ± 5.0 | kcal/mol | D-EA | Bengali and Leopold, 1992 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 356.0 ± 5.1 | kcal/mol | H-TS | Bengali and Leopold, 1992 | gas phase |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
View reactions leading to CH4Si+ (ion structure unspecified)
De-protonation reactions
CH3Si- + = CH4Si
By formula: CH3Si- + H+ = CH4Si
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 364.2 ± 5.0 | kcal/mol | D-EA | Bengali and Leopold, 1992 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 356.0 ± 5.1 | kcal/mol | H-TS | Bengali and Leopold, 1992 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bengali and Leopold, 1992
Bengali, A.A.; Leopold, D.G.,
Negative Ion Photoelectron Spectroscopy of CH2=SiH and CH3Si,
J. Am. Chem. Soc., 1992, 114, 23, 9192, https://doi.org/10.1021/ja00049a064
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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