Hydrazine

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Gas phase thermochemistry data

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas22.79kcal/molReviewChase, 1998Data last reviewed in December, 1965
Δfgas36. ± 2.kcal/molIonWillis, Lossing, et al., 1976Appearance potentials; ALS
Δfgas12.05kcal/molCmCole and Gilbert, 1951ALS
Quantity Value Units Method Reference Comment
Δcgas-148.68kcal/molCmCole and Gilbert, 1951ALS
Quantity Value Units Method Reference Comment
gas,1 bar57.041cal/mol*KReviewChase, 1998Data last reviewed in December, 1965

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 800. to 2000.2000. to 6000.
A 8.40879629.01554
B 22.957121.151262
C -9.680044-0.182364
D 1.5937070.010333
E -0.208947-9.748208
F 18.64042-2.720149
G 59.6140172.97897
H 22.7900122.79001
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1965 Data last reviewed in December, 1965

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 38

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References

Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Willis, Lossing, et al., 1976
Willis, C.; Lossing, F.P.; Back, R.A., The heat of formation of N2H2 and the proton affinity of N2, Can. J. Chem., 1976, 54, 1-3. [all data]

Cole and Gilbert, 1951
Cole, L.G.; Gilbert, E.C., The heats of combustion of some nitrogen compounds and the apparent energy of the N-N bond, J. Am. Chem. Soc., 1951, 73, 5423-5427. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), References