Hydrazine
- Formula: H4N2
- Molecular weight: 32.0452
- IUPAC Standard InChIKey: OAKJQQAXSVQMHS-UHFFFAOYSA-N
- CAS Registry Number: 302-01-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Levoxine; N2H4; Diamine; Hydrazyna; Rcra waste number U133; Hydrazine, anhydrous; Hydrazine base; Nitrogen hydride, (N2H4); Oxytreat 35
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Gas phase thermochemistry data
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 22.79 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1965 |
ΔfH°gas | 36. ± 2. | kcal/mol | Ion | Willis, Lossing, et al., 1976 | Appearance potentials; ALS |
ΔfH°gas | 12.05 | kcal/mol | Cm | Cole and Gilbert, 1951 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°gas | -148.68 | kcal/mol | Cm | Cole and Gilbert, 1951 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 57.041 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1965 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 800. to 2000. | 2000. to 6000. |
---|---|---|
A | 8.408796 | 29.01554 |
B | 22.95712 | 1.151262 |
C | -9.680044 | -0.182364 |
D | 1.593707 | 0.010333 |
E | -0.208947 | -9.748208 |
F | 18.64042 | -2.720149 |
G | 59.61401 | 72.97897 |
H | 22.79001 | 22.79001 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in December, 1965 | Data last reviewed in December, 1965 |
Mass spectrum (electron ionization)
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 38 |
References
Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Willis, Lossing, et al., 1976
Willis, C.; Lossing, F.P.; Back, R.A.,
The heat of formation of N2H2 and the proton affinity of N2,
Can. J. Chem., 1976, 54, 1-3. [all data]
Cole and Gilbert, 1951
Cole, L.G.; Gilbert, E.C.,
The heats of combustion of some nitrogen compounds and the apparent energy of the N-N bond,
J. Am. Chem. Soc., 1951, 73, 5423-5427. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔcH°gas Enthalpy of combustion of gas at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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