CS2+


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CS2+ + Carbon disulfide = (CS2+ • Carbon disulfide)

By formula: CS2+ + CS2 = (CS2+ • CS2)

Quantity Value Units Method Reference Comment
Δr24.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase
Δr17.5kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr21.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(CS2+ • 2Carbon disulfide) + Carbon disulfide = (CS2+ • 3Carbon disulfide)

By formula: (CS2+ • 2CS2) + CS2 = (CS2+ • 3CS2)

Quantity Value Units Method Reference Comment
Δr4.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Δr3.9kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(CS2+ • Carbon disulfide) + Carbon disulfide = (CS2+ • 2Carbon disulfide)

By formula: (CS2+ • CS2) + CS2 = (CS2+ • 2CS2)

Quantity Value Units Method Reference Comment
Δr6.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr4.4kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(CS2+ • 3Carbon disulfide) + Carbon disulfide = (CS2+ • 4Carbon disulfide)

By formula: (CS2+ • 3CS2) + CS2 = (CS2+ • 4CS2)

Quantity Value Units Method Reference Comment
Δr2.6kcal/molPIOno, Linn, et al., 1980gas phase

CS2+ + Carbonyl sulfide = (CS2+ • Carbonyl sulfide)

By formula: CS2+ + COS = (CS2+ • COS)

Quantity Value Units Method Reference Comment
Δr5.8kcal/molPIOno, Osuch, et al., 1981gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

CS2+ + Carbonyl sulfide = (CS2+ • Carbonyl sulfide)

By formula: CS2+ + COS = (CS2+ • COS)

Quantity Value Units Method Reference Comment
Δr5.8kcal/molPIOno, Osuch, et al., 1981gas phase

CS2+ + Carbon disulfide = (CS2+ • Carbon disulfide)

By formula: CS2+ + CS2 = (CS2+ • CS2)

Quantity Value Units Method Reference Comment
Δr24.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr21.9kcal/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase
Δr17.5kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr23.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr21.9cal/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase

(CS2+ • Carbon disulfide) + Carbon disulfide = (CS2+ • 2Carbon disulfide)

By formula: (CS2+ • CS2) + CS2 = (CS2+ • 2CS2)

Quantity Value Units Method Reference Comment
Δr6.5kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr4.4kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr21.cal/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(CS2+ • 2Carbon disulfide) + Carbon disulfide = (CS2+ • 3Carbon disulfide)

By formula: (CS2+ • 2CS2) + CS2 = (CS2+ • 3CS2)

Quantity Value Units Method Reference Comment
Δr4.9kcal/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Δr3.9kcal/molPIOno, Linn, et al., 1980gas phase
Quantity Value Units Method Reference Comment
Δr17.cal/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(CS2+ • 3Carbon disulfide) + Carbon disulfide = (CS2+ • 4Carbon disulfide)

By formula: (CS2+ • 3CS2) + CS2 = (CS2+ • 4CS2)

Quantity Value Units Method Reference Comment
Δr2.6kcal/molPIOno, Linn, et al., 1980gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Frontier-Controlled Structures of the Gas-Phase A+-(CS2)n Clusters ,A+- = S2+, CS2+, S2-, and CS2-, J. Phys. Chem., 1994, 98, 7, 1802, https://doi.org/10.1021/j100058a014 . [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry, J. Chem. Phys., 1977, 66, 10, 4527, https://doi.org/10.1063/1.433706 . [all data]

Ono, Linn, et al., 1980
Ono, Y.; Linn, S.H.; Prest, H.F.; Gress, M.E.; Ng, C.Y., Molecular beam photoionization study of carbon disulfide, carbon disulfide dimer and clusters, J. Chem. Phys., 1980, 73, 2523. [all data]

Ono, Osuch, et al., 1981
Ono, Y.; Osuch, E.A.; Ng, C.Y., Molecular beam photoionization study of OCS, (OCS)2, (OCS)3, and OCS.CS2, J. Chem. Phys., 1981, 74, 1645. [all data]


Notes

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