tetrahexylammonium perchlorate
- Formula: C24H52ClNO4
- Molecular weight: 454.127
- IUPAC Standard InChIKey: RLCKPGXHGKSGOS-UHFFFAOYSA-M
- CAS Registry Number: 4656-81-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Tetra-n-hexylammonium perchlorate
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Condensed phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
744. | 298.15 | Andrews and Gordon, 1973 | crystaline, IV phase; T = 300 to 382 K. |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 383. | K | N/A | Coker, Ambrose, et al., 1970 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.5 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 379.22 | K | N/A | Andrews and Gordon, 1973, 2 | Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
22.990 | 333.57 | crystaline, IV | crystaline, III | Andrews and Gordon, 1973 | DH |
5.839 | 355.91 | crystaline, III | crystaline, II | Andrews and Gordon, 1973 | DH |
2.658 | 367.51 | crystaline, II | crystaline, I | Andrews and Gordon, 1973 | DH |
16.350 | 379.18 | crystaline, I | liquid | Andrews and Gordon, 1973 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
68.9 | 333.57 | crystaline, IV | crystaline, III | Andrews and Gordon, 1973 | DH |
16.4 | 355.91 | crystaline, III | crystaline, II | Andrews and Gordon, 1973 | DH |
7.2 | 367.51 | crystaline, II | crystaline, I | Andrews and Gordon, 1973 | DH |
43.1 | 379.18 | crystaline, I | liquid | Andrews and Gordon, 1973 | DH |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Andrews and Gordon, 1973
Andrews, J.T.S.; Gordon, J.E.,
Adiabatic calorimetry of organic salts. Tetra-n-hexylammonium perchlorate,
J. Chem. Soc. Faraday Trans., 1973, I 69, 546-554. [all data]
Coker, Ambrose, et al., 1970
Coker, T.G.; Ambrose, J.; Janz, G.J.,
Fusion properties of some ionic quaternary ammonium compounds.,
J. Am. Chem. Soc., 1970, 92, 5293. [all data]
Andrews and Gordon, 1973, 2
Andrews, J.T.S.; Gordon, J.E.,
Adiabatic calorimetry of organic salts tetra-n-hexylammonium perchlorate,
J. Chem. Soc. Faraday Trans. 1, 1973, 69, 546. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid Tfus Fusion (melting) point Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.