Manganic acetylacetonate

• Formula: C₁₅H₂₁MnO₆
• Molecular weight: 352.2617
• IUPAC Standard InChI: InChI=1S/3C5H8O2.Mn/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; Copy

  
• IUPAC Standard InChIKey: HYZQBNDRDQEWAN-LNTINUHCSA-K Copy
• CAS Registry Number: 14284-89-0
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Manganese(III) 2,4-pentanedionate; (CH3COCHCOCH3)3Mn; Manganese(III)acetylacetonate; Manganese, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-; Manganese tris(acetylacetonate); Manganese(3+) acetylacetonate; Manganese, tris(2,4-pentanedionato)-; Tris(acetylacetonato)manganese; Tris(2,4-pentanedionato)manganese; Manganese, tris(2,4-pentanedionato-O,O'-); NSC 82319; Manganese, tris(2,4-pentanedionato-κO,κO')-, (OC-6-11)-; Manganese, tris(2,4-pentanedionato-κO2,κO4)-, (OC-6-11)-; manganese tris(4-oxopent-2-en-2-oate)
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• Information on this page:
  • Phase change data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Enthalpy of fusion

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I., Thermal behavior of 3d transition metal acetylacetonates, Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]

Da Silva and Ferrao, 1988
Da Silva, Manuel A.V. Ribeiro; Ferrao, M. Luisa C.C.H., Standard enthalpies of formation of tris(β-diketonate)manganese(III) complexes: the mean (Mn---O) bond-dissociation enthalpies, Can. J. Chem., 1988, 66, 4, 651-654, https://doi.org/10.1139/v88-112 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Hill and Irving, 1968
Hill, J.O.; Irving, R.J., The heat of formation of tris(acetylacetonato)manganese(III) and the manganese?oxygen bond energy, J. Chem. Soc., A, 1968, 3116, https://doi.org/10.1039/j19680003116 . [all data]

Maslowska and Baranowski, 1981
Maslowska, J.; Baranowski, J.B., Chemia Analityczna, 1981, 26, 1017. [all data]

Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H., Dampfdruckbestimmung von Acetylacetonaten, Zeitschrift für Physikalische Chemie, 1970, 73, 4₆, 314-320, https://doi.org/10.1524/zpch.1970.73.4₆.314 . [all data]

Sabolovic, Mrak, et al., 2004
Sabolovic, Jasmina; Mrak, Zeljko; Kostrun, Sanja; Janekovic, August, Is the Enthalpy of Fusion of Tris(acetylacetonato)metal(III) Complexes Affected by Their Potential Energy in the Crystal State?, Inorg. Chem., 2004, 43, 26, 8479-8489, https://doi.org/10.1021/ic048900u . [all data]

Notes

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• Symbols used in this document:
  

  ΔfusH	Enthalpy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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