α-D-Glucose

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
7.5096414.Parks and Thomas, 1934DH
7.510414.Domalski and Hearing, 1996AC
8.20423.2Schwarz, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
18.1414.Parks and Thomas, 1934DH

Reaction thermochemistry data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H11O6- + Hydrogen cation = α-D-Glucose

By formula: C6H11O6- + H+ = C6H12O6

Quantity Value Units Method Reference Comment
Δr332.0 ± 4.0kcal/molIMRBCai and Cole, 2002gas phase

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

Mass spectrum
For Zoom
1.) Enter the desired X axis range (e.g., 100, 200)
2.) Check here for automatic Y scaling
3.) Press here to zoom

Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin W.E. FRANKLIN, SOUTH. REG. RES. CENT., NEW ORLEANS, LA., USA
NIST MS number 98151

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Parks and Thomas, 1934
Parks, G.S.; Thomas, S.B., The heat capacities of crystalline, glassy and undercooled liquid glucose, J. Am. Chem. Soc., 1934, 56, 1423. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Schwarz, 1996
Schwarz, Frederick P., Enthalpy of solution of carbohydrates using a modified differential scanning calorimeter, J Solution Chem, 1996, 25, 5, 471-484, https://doi.org/10.1007/BF00972993 . [all data]

Cai and Cole, 2002
Cai, Y.; Cole, R.B., Stabilization of anionic adducts in negative ion electrospray mass spectrometry, Anal. Chem., 2002, 74, 5, 985-991, https://doi.org/10.1021/ac0108818 . [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References