Ferric tris(acetylacetonate)
- Formula: C15H21FeO6
- Molecular weight: 353.169
- IUPAC Standard InChIKey: AQBLLJNPHDIAPN-LNTINUHCSA-K
- CAS Registry Number: 14024-18-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Iron, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-; (Acetylacetonato)iron(iii); Iron, tris(2,4-pentanedionato)-; Ferric acetylacetonate; Ferric tris(acetoacetonate); Iron acetylacetonate; Iron triacetylacetonate; Iron tris(acetoacetonate); Iron tris(acetylacetonate); Iron tris(2,4-pentanedionate); Iron(iii) acetylacetonate; Iron(3+) acetylacetonate; Tris(acetylacetonato)iron; Tris(acetylacetone)iron; Tris(2,4-pentanedionato)iron; Iron(III) 2,4-pentanedionate; Ferric(III) acetylacetonate; Ferric triacetylacetonate; Acetope Fe(II); Nacem Iron; NSC 43622; tris(pentane-2,4-dionato)iron(II)
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Phase change data
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 461. | K | N/A | Murray and Hill, 1984 | Uncertainty assigned by TRC = 1. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 128.6 ± 0.9 | kJ/mol | N/A | Ribeiro da Silva, Monte, et al., 1996 | AC |
ΔsubH° | 126.4 ± 3.1 | kJ/mol | ME | Malkerova, Alikhanyan, et al., 1990 | Based on data from 309. to 360. K.; AC |
ΔsubH° | 138.4 ± 5.2 | kJ/mol | C | Murata, Sakiyama, et al., 1985 | AC |
ΔsubH° | 65.3 ± 3.3 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Hill and Irving, 1968.; AC |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
112. | 413. to 443. | TGA | Fahlman and Barron, 2000 | AC |
124.6 ± 0.9 | 378. | TE,ME | Ribeiro da Silva, Monte, et al., 1996 | Based on data from 369. to 388. K.; AC |
114.2 ± 1.5 | 338. to 355. | N/A | Gerasimova, Gerasimova, et al., 1992 | AC |
100. | 395. | T | Maslowska and Baranowski, 1981 | AC |
114.2 | 385. | N/A | Götze, Bloss, et al., 1970 | AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
30.1 | 459. | DSC | Sabolovic, Mrak, et al., 2004 | AC |
25.3 | 460. | DSC | Sabolovic, Mrak, et al., 2004 | AC |
22.6 | 462. | N/A | Murray and Hill, 1984, 2 | AC |
25.9 | 454. | N/A | Melia and Merrifield, 1970 | AC |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-9155 |
NIST MS number | 230421 |
References
Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Murray and Hill, 1984
Murray, J.P.; Hill, J.O.,
DSC determination of the fusion and sublimation enthalpy of tris(2,4-pentanedionato)chromium(III) and iron(III),
Thermochim. Acta, 1984, 72, 341. [all data]
Ribeiro da Silva, Monte, et al., 1996
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Huinink, Jan,
Vapour pressures and standard molar enthalpies of sublimation of two crystalline iron(III) β-diketonates. The mean molar (Fe-O) bond-dissociation enthalpies,
The Journal of Chemical Thermodynamics, 1996, 28, 4, 413-419, https://doi.org/10.1006/jcht.1996.0041
. [all data]
Malkerova, Alikhanyan, et al., 1990
Malkerova, I.P.; Alikhanyan, A.S.; Sevast'yanov, V.G.; Grinberg, Ya.Kh.; Gorgoraki, V.I.,
Thermal behavior of 3d transition metal acetylacetonates,
Zh. Neorg. Khim., 1990, 35, 2, 413. [all data]
Murata, Sakiyama, et al., 1985
Murata, S.; Sakiyama, M.; Seki, S.,
Sublimation calorimetric studies using a calvet microcalorimeter,
Thermochimica Acta, 1985, 88, 1, 121-126, https://doi.org/10.1016/0040-6031(85)85419-8
. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Hill and Irving, 1968
Hill, J.O.; Irving, R.J.,
The heat of formation of tris(acetylacetonato)iron(III) and the metal?oxygen bond energy,
J. Chem. Soc., A, 1968, 1052, https://doi.org/10.1039/j19680001052
. [all data]
Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R.,
Substituent effects on the volatility of metal ?-diketonates,
Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M
. [all data]
Gerasimova, Gerasimova, et al., 1992
Gerasimova, P.A.; Gerasimova, A.I.; Fedotova, N.E.; Morozova, N.B.; Igumenov, I.K.,
Thermochemical study of iron(III) tris(β-diketonates),
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1992, 35, 9, 38. [all data]
Maslowska and Baranowski, 1981
Maslowska, J.; Baranowski, J.B.,
Chemia Analityczna, 1981, 26, 1017. [all data]
Götze, Bloss, et al., 1970
Götze, H.-J.; Bloss, K.; Molketin, H.,
Dampfdruckbestimmung von Acetylacetonaten,
Zeitschrift für Physikalische Chemie, 1970, 73, 46, 314-320, https://doi.org/10.1524/zpch.1970.73.46.314
. [all data]
Sabolovic, Mrak, et al., 2004
Sabolovic, Jasmina; Mrak, Zeljko; Kostrun, Sanja; Janekovic, August,
Is the Enthalpy of Fusion of Tris(acetylacetonato)metal(III) Complexes Affected by Their Potential Energy in the Crystal State?,
Inorg. Chem., 2004, 43, 26, 8479-8489, https://doi.org/10.1021/ic048900u
. [all data]
Murray and Hill, 1984, 2
Murray, J.P.; Hill, J.O.,
DSC determination of the fusion and sublimation enthalpy of tris(2,4-pentanedionato)chromium(III) and iron(III),
Thermochimica Acta, 1984, 72, 3, 341-347, https://doi.org/10.1016/0040-6031(84)85092-3
. [all data]
Melia and Merrifield, 1970
Melia, T.P.; Merrifield, R.,
Thermal properties of transition metal compounds,
Journal of Inorganic and Nuclear Chemistry, 1970, 32, 8, 2573-2579, https://doi.org/10.1016/0022-1902(70)80304-9
. [all data]
Notes
Go To: Top, Phase change data, Mass spectrum (electron ionization), References
- Symbols used in this document:
Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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