Tetraethyllead

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas26.2 ± 1.2kcal/molReviewMartinho Simões 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil455.7KN/ADibrivnyi, Dolbneva, et al., 1986Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus142.94KN/AStaveley, Warren, et al., 1954Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Ttriple141.49KN/ARabinovich, Nistratov, et al., 1989Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple139.41KN/ARabinovich, Nistratov, et al., 1989Metastable crystal phase; Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Δvap13.5 ± 0.24kcal/molCC-RBAbraham and Irving, 1980Other values for the enthalpy of vaporization have been reported: 13.6 ± 0.60 kcal/mol Buckler and Norrish, 1936 and 13.4 ± 0.50 kcal/mol Scott, 1972.; MS
Δvap13.5 ± 0.24kcal/molCAbraham and Irving, 1980, 2AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Reference Comment
13.7326.Stull, 1947Based on data from 311. to 456. K.; AC
13.5308.Buckler and Norrish, 1936, 2Based on data from 273. to 343. K.; AC
13.6387.Jones, Evans, et al., 1935Based on data from 351. to 423. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
311.6 to 456.5.017341984.384-60.506Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
2.101142.94Staveley, Warren, et al., 1954, 2DH
2.18141.4Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
14.70142.94Staveley, Warren, et al., 1954, 2DH

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
90.8crystaline, IIIliquidRabinovich, Nistratov, et al., 1989, 2Glass/supercooled liquid transition.; DH

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
2.177141.4crystaline, IIliquidRabinovich, Nistratov, et al., 1989, 2DH
2.173139.41crystaline, IliquidRabinovich, Nistratov, et al., 1989, 2DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
15.40141.4crystaline, IIliquidRabinovich, Nistratov, et al., 1989, 2DH
15.59139.41crystaline, IliquidRabinovich, Nistratov, et al., 1989, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin API 0699
NIST MS number 15241

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References

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Dibrivnyi, Dolbneva, et al., 1986
Dibrivnyi, V.N.; Dolbneva, T.N.; Dikii, M.A., Saturated vapor pressure and vaporization enthalpies of aromatic peroxides in Vses. Konf. po Kalorimetrii i Khim. Termodinamike, 11th, Novosibirsk, Nr 2, p 115, 1986. [all data]

Staveley, Warren, et al., 1954
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J., Some Thermodynamic Properties of Compounds of the Formula MX4 II. Tetraalkyl Compounds, J. Chem. Soc., 1954, 1954, 1992. [all data]

Rabinovich, Nistratov, et al., 1989
Rabinovich, I.B.; Nistratov, V.P.; Sheiman, M.S.; Karataev, E.N.; Kamelova, G.P.; Feshchenko, I.A., Heat capacity, phase transitions, and thermodynamic functions of tetraethyllead, Zh. Fiz. Khim., 1989, 63, 2520-4. [all data]

Abraham and Irving, 1980
Abraham, M.H.; Irving, R.J., J. Chem. Thermodyn., 1980, 12, 539. [all data]

Buckler and Norrish, 1936
Buckler, E.J.; Norrish, R.G.W., J. Chem. Soc., 1936, 1567.. [all data]

Scott, 1972
Scott, D.W., J. Chem. Thermodyn., 1972, 4, 99. [all data]

Abraham and Irving, 1980, 2
Abraham, M.H.; Irving, R.J., Enthalpies of vaporization of tetramethyltin, tetraethyltin, tetra-n-propyltin, and tetraethyl-lead, and a survey of the Group IV tetramethyl and tetraethyl compounds, The Journal of Chemical Thermodynamics, 1980, 12, 6, 539-544, https://doi.org/10.1016/0021-9614(80)90183-4 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Buckler and Norrish, 1936, 2
Buckler, E.J.; Norrish, R.G., 346. The vapour-pressure curve of tetraethyl-lead from 0«65533» to 70«65533», J. Chem. Soc., 1936, 1567, https://doi.org/10.1039/jr9360001567 . [all data]

Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C., 10. Some physical properties of the alkyl compounds of mercury, tin, and lead, J. Chem. Soc., 1935, 39, https://doi.org/10.1039/jr9350000039 . [all data]

Staveley, Warren, et al., 1954, 2
Staveley, L.A.K.; Warren, J.B.; Paget, H.P.; Dowrick, D.J., Some thermodynamic properties of compounds of the formula MX4. Part II. Tetra-alkyl compounds, 1954, J. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Rabinovich, Nistratov, et al., 1989, 2
Rabinovich, I.B.; Nistratov, V.P.; Sheiman, M.S.; Karataev, E.N.; Kamelova, G.P.; Feshchenko, I.A., Heat capacity, phase transitions, and thermodynamic function of tetraethyllead, Zhur. Fiz. Khim., 1989, 63, 2520-2524. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References