fluorine
- Formula: F2
- Molecular weight: 37.9968064
- IUPAC Standard InChI: InChI=1S/F2/c1-2
- IUPAC Standard InChIKey: PXGOKWXKJXAPGV-UHFFFAOYSA-N
- CAS Registry Number: 7782-41-4
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| S°gas,1 bar | 48.468 ± 0.001 | cal/mol*K | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
| S°gas,1 bar | 48.470 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1982 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. to 6000. |
|---|---|
| A | 7.515560 |
| B | 2.010954 |
| C | -0.664161 |
| D | 0.052128 |
| E | -0.050472 |
| F | -2.493452 |
| G | 56.71056 |
| H | 0.000000 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in June, 1982 |
Phase change data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tboil | 85.2 | K | N/A | Streng, 1971 | Uncertainty assigned by TRC = 0.3 K; TRC |
| Quantity | Value | Units | Method | Reference | Comment |
| Tfus | 55.2 | K | N/A | Streng, 1971 | Uncertainty assigned by TRC = 0.3 K; TRC |
| Quantity | Value | Units | Method | Reference | Comment |
| Tc | 144. | K | N/A | Cady and Hildebrand, 1930 | Uncertainty assigned by TRC = 1. K; in glass capillary tube; TRC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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| Temperature (K) | A | B | C | Reference | Comment |
|---|---|---|---|---|---|
| 53.99 to 143.99 | 4.01784 | 322.067 | -4.748 | Straty and Prydz, 1970 | Coefficents calculated by NIST from author's data. |
| 50. to 85.3 | 4.61744 | 417.961 | 5.415 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A.,
CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Streng, 1971
Streng, A.G.,
Miscibility and Compatibility of Some Liquid and Solidified Gases at Low Temperature,
J. Chem. Eng. Data, 1971, 16, 357. [all data]
Cady and Hildebrand, 1930
Cady, G.H.; Hildebrand, J.H.,
The Vapor Pressure and Critical Temperature of Fluorine,
J. Am. Chem. Soc., 1930, 52, 3839. [all data]
Straty and Prydz, 1970
Straty, G.C.; Prydz, R.,
The Vapor Pressure of Liquid Fluorine,
Adv. Cryog. Eng., 1970, 15, 36-41. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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