Methane
- Formula: CH4
- Molecular weight: 16.0425
- IUPAC Standard InChIKey: VNWKTOKETHGBQD-UHFFFAOYSA-N
- CAS Registry Number: 74-82-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Marsh gas; Methyl hydride; CH4; Fire Damp; R 50; Biogas; R 50 (refrigerant)
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Gas phase thermochemistry data
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -74.87 | kJ/mol | Review | Chase, 1998 | Data last reviewed in March, 1961 |
ΔfH°gas | -74.6 ± 0.3 | kJ/mol | Review | Manion, 2002 | adopted recommendation of Gurvich, Veyts, et al., 1991; DRB |
ΔfH°gas | -74.5 ± 0.4 | kJ/mol | Ccb | Pittam and Pilcher, 1972 | ALS |
ΔfH°gas | -74.85 ± 0.31 | kJ/mol | Ccb | Prosen and Rossini, 1945 | Hf derived from Heat of Hydrogenation; ALS |
ΔfH°gas | -73.4 ± 1.1 | kJ/mol | Ccb | Roth and Banse, 1932 | Reanalyzed by Cox and Pilcher, 1970, Original value = -75.19 kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°gas | -890.7 ± 0.4 | kJ/mol | Ccb | Pittam and Pilcher, 1972 | Corresponding ΔfHºgas = -74.48 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°gas | -890.35 ± 0.30 | kJ/mol | Ccb | Prosen and Rossini, 1945 | Hf derived from Heat of Hydrogenation; Corresponding ΔfHºgas = -74.822 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°gas | -891.8 ± 1.1 | kJ/mol | Ccb | Roth and Banse, 1932 | Reanalyzed by Cox and Pilcher, 1970, Original value = -887.3 ± 1.0 kJ/mol; Corresponding ΔfHºgas = -73.39 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°gas | -890.16 ± 0.30 | kJ/mol | Cm | Rossini, 1931 | Corresponding ΔfHºgas = -75.010 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°gas | 188.66 ± 0.42 | J/mol*K | N/A | Colwell J.H., 1963 | The calorimetric value is significantly higher than the statistically calculated entropy, 186.26 J/mol*K, which remains the best value for use in thermodynamic calculations [ Vogt G.J., 1976, Friend D.G., 1989, Gurvich, Veyts, et al., 1989]. Earlier the value of 185.3 J/mol*K was calculated from experimental data [ Giauque W.F., 1931]. The value of S(298.15 K)=185.94 J/mol*K was obtained by high accuracy ab initio calculation [ East A.L.L., 1997].; GT |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 186.25 | J/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1961 |
Constant pressure heat capacity of gas
Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
34.92 ± 0.25 | 279. | Halford J.O., 1957 | GT |
Constant pressure heat capacity of gas
Cp,gas (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
33.28 | 100. | Gurvich, Veyts, et al., 1989 | p=1 bar. Because of more precise method of calculation, the recommended values are more accurate, especially at high temperatures, than those obtained by [ McDowell R.S., 1963] and often regarded as reference data [ Friend D.G., 1989].; GT |
33.51 | 200. | ||
35.69 | 298.15 | ||
35.76 | 300. | ||
40.63 | 400. | ||
46.63 | 500. | ||
52.74 | 600. | ||
58.60 | 700. | ||
64.08 | 800. | ||
69.14 | 900. | ||
73.75 | 1000. | ||
77.92 | 1100. | ||
81.68 | 1200. | ||
85.07 | 1300. | ||
88.11 | 1400. | ||
90.86 | 1500. | ||
93.33 | 1600. | ||
95.58 | 1700. | ||
97.63 | 1800. | ||
99.51 | 1900. | ||
101.24 | 2000. | ||
102.83 | 2100. | ||
104.31 | 2200. | ||
105.70 | 2300. | ||
107.00 | 2400. | ||
108.23 | 2500. | ||
109.39 | 2600. | ||
110.50 | 2700. | ||
111.56 | 2800. | ||
112.57 | 2900. | ||
113.55 | 3000. |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 1300. | 1300. to 6000. |
---|---|---|
A | -0.703029 | 85.81217 |
B | 108.4773 | 11.26467 |
C | -42.52157 | -2.114146 |
D | 5.862788 | 0.138190 |
E | 0.678565 | -26.42221 |
F | -76.84376 | -153.5327 |
G | 158.7163 | 224.4143 |
H | -74.87310 | -74.87310 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in March, 1961 | Data last reviewed in March, 1961 |
Phase change data
Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 111. ± 2. | K | AVG | N/A | Average of 13 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 85.7 | K | N/A | Streng, 1971 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tfus | 90.6 | K | N/A | Van't Zelfde, Omar, et al., 1968 | Uncertainty assigned by TRC = 0.3 K; TRC |
Tfus | 91.2 | K | N/A | Timmermans, 1935 | Uncertainty assigned by TRC = 2. K; TRC |
Tfus | 90.6 | K | N/A | Clusius, 1929 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tfus | 90.5 | K | N/A | Eucken and Karwat, 1924 | Uncertainty assigned by TRC = 0.2 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 90.67 ± 0.03 | K | AVG | N/A | Average of 25 out of 32 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ptriple | 0.1169 ± 0.0006 | bar | AVG | N/A | Average of 20 out of 23 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 190.6 ± 0.3 | K | AVG | N/A | Average of 19 out of 23 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 46.1 ± 0.3 | bar | AVG | N/A | Average of 16 out of 21 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.09860 | l/mol | N/A | Ambrose and Tsonopoulos, 1995 | |
Vc | 0.09852 | l/mol | N/A | Younglove and Ely, 1987 | TRC |
Vc | 0.100 | l/mol | N/A | Terry, Lynch, et al., 1969 | Uncertainty assigned by TRC = 0.001 l/mol; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 10.1 ± 0.2 | mol/l | AVG | N/A | Average of 16 out of 17 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
8.519 | 99.54 | N/A | Vogt and Pitzer, 1976 | P = 2.81 kPa Data from Frank and Clusius, 1937 and 39FRA/CLU.; DH |
8.6 | 101. | N/A | Stock, Henning, et al., 2006 | Based on data from 92. to 110. K. See also Boublik, Fried, et al., 1984.; AC |
8.6 | 105. | A | Stephenson and Malanowski, 1987 | Based on data from 90. to 120. K.; AC |
8.4 | 134. | A | Stephenson and Malanowski, 1987 | Based on data from 115. to 149. K.; AC |
8.7 | 174. | A | Stephenson and Malanowski, 1987 | Based on data from 148. to 189. K.; AC |
8.17 | 111.7 | N/A | Majer and Svoboda, 1985 | |
8.6 | 112. | N/A | Ott, Goates, et al., 1972 | Based on data from 91. to 127. K. See also Boublik, Fried, et al., 1984.; AC |
8.5 | 175. | N/A | Ott, Goates, et al., 1972 | Based on data from 91. to 190. K.; AC |
8.1 | 137. | N/A | Reid, 1972 | AC |
8.6 | 175. | N/A | Ambrose, Counsell, et al., 1970 | Based on data from 100. to 190. K.; AC |
8.2 | 112. | C | Hestermans and White, 1961 | AC |
7.5 | 130. | C | Hestermans and White, 1961 | AC |
5.9 | 160. | C | Hestermans and White, 1961 | AC |
4.0 | 180. | C | Hestermans and White, 1961 | AC |
8.5 | 149. | N/A | Hestermans and White, 1961 | Based on data from 109. to 189. K.; AC |
8.5 ± 0.1 | 99. | N/A | Frank and Clusius, 1939 | AC |
Enthalpy of vaporization
ΔvapH = A exp(-αTr)
(1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kJ/mol)
Tr = reduced temperature (T / Tc)
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Temperature (K) | 112. to 180. |
---|---|
A (kJ/mol) | 10.11 |
α | -0.22 |
β | 0.388 |
Tc (K) | 190.6 |
Reference | Majer and Svoboda, 1985 |
Entropy of vaporization
ΔvapS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
85.58 | 99.54 | Vogt and Pitzer, 1976 | P; DH |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
90.99 to 189.99 | 3.9895 | 443.028 | -0.49 | Prydz and Goodwin, 1972 | Coefficents calculated by NIST from author's data. |
96.89 to 110.19 | 2.00253 | 125.819 | -48.823 | Regnier, 1972 | Coefficents calculated by NIST from author's data. |
93.04 to 107.84 | 3.80235 | 403.106 | -5.479 | Cutler and Morrison, 1965 | Coefficents calculated by NIST from author's data. |
110.00 to 190.5 | 4.22061 | 516.689 | 11.223 | Hestermans and White, 1961 | Coefficents calculated by NIST from author's data. |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
9.7 | 72. | N/A | Stephenson and Malanowski, 1987 | Based on data from 53. to 91. K.; AC |
9.2 | 72. | N/A | Bondi, 1963 | Based on data from 54. to 90. K. See also Armstrong, Brickwedde, et al., 1955.; AC |
10.0 | 84. | N/A | Jones, 1960 | Based on data from 79. to 89. K.; AC |
9.7 | 63. | A,MS | Tickner and Lossing, 1951 | Based on data from 48. to 78. K.; AC |
9.62 | 77. | A | Stull, 1947 | Based on data from 67. to 88. K.; AC |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.09355 | 20.53 | crystaline, II | crystaline, I | Vogt and Pitzer, 1976 | Lambda transition.; DH |
0.9392 | 90.67 | crystaline, I | liquid | Vogt and Pitzer, 1976 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
4.557 | 20.53 | crystaline, II | crystaline, I | Vogt and Pitzer, 1976 | Lambda; DH |
10.36 | 90.67 | crystaline, I | liquid | Vogt and Pitzer, 1976 | DH |
Mass spectrum (electron ionization)
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY |
NIST MS number | 61313 |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Manion, 2002
Manion, J.A.,
Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons,
J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703
. [all data]
Gurvich, Veyts, et al., 1991
Thermodynamic Properties of Individual Substances, 4th edition, Volume 2, Gurvich, L.V.; Veyts, I.V.; Alcock, C.B.;, ed(s)., Hemisphere, New York, 1991. [all data]
Pittam and Pilcher, 1972
Pittam, D.A.; Pilcher, G.,
Measurements of heats of combustion by flame calorimetry. Part 8.-Methane, ethane, propane, n-butane and 2-methylpropane,
J. Chem. Soc. Faraday Trans. 1, 1972, 68, 2224-2229. [all data]
Prosen and Rossini, 1945
Prosen, E.J.; Rossini, F.D.,
Heats of combustion and formation of the paraffin hydrocarbons at 25° C,
J. Res. NBS, 1945, 263-267. [all data]
Roth and Banse, 1932
Roth, W.A.; Banse, H.,
Die verbrennungs- und bildungswarme von kohlenoxyd und methan,
Arch. Eisenhutten., 1932, 6, 43-46. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Rossini, 1931
Rossini, F.D.,
The heats of combustion of methane and carbon monoxide,
J. Res. NBS, 1931, 6, 37-49. [all data]
Colwell J.H., 1963
Colwell J.H.,
Thermodynamic properties of CH4 and CD4. Interpretation of the properties of solid,
J. Chem. Phys., 1963, 39, 635-653. [all data]
Vogt G.J., 1976
Vogt G.J.,
Entropy and heat capacity of methane; spin-species conversion,
J. Chem. Thermodyn., 1976, 8, 1011-1031. [all data]
Friend D.G., 1989
Friend D.G.,
Thermophysical properties of methane,
J. Phys. Chem. Ref. Data, 1989, 18, 583-638. [all data]
Gurvich, Veyts, et al., 1989
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B.,
Thermodynamic Properties of Individual Substances, 4th ed.; Vols. 1 and 2, Hemisphere, New York, 1989. [all data]
Giauque W.F., 1931
Giauque W.F.,
The entropies of methane and ammonia,
Phys. Rev., 1931, 38, 196-197. [all data]
East A.L.L., 1997
East A.L.L.,
Ab initio statistical thermodynamical models for the computation of third-law entropies,
J. Chem. Phys., 1997, 106, 6655-6674. [all data]
Halford J.O., 1957
Halford J.O.,
Standard heat capacities of gaseous methanol, ethanol, methane and ethane at 279 K by thermal conductivity,
J. Phys. Chem., 1957, 61, 1536-1539. [all data]
McDowell R.S., 1963
McDowell R.S.,
Thermodynamic functions of methane,
J. Chem. Eng. Data, 1963, 8, 547-548. [all data]
Streng, 1971
Streng, A.G.,
Miscibility and Compatibility of Some Liquid and Solidified Gases at Low Temperature,
J. Chem. Eng. Data, 1971, 16, 357. [all data]
Van't Zelfde, Omar, et al., 1968
Van't Zelfde, P.; Omar, M.H.; LePair-Schroten, H.G.M.; Dokoupil, Z.,
Solid-liquid equilibrium diagram for the argon + methane system.,
Physica (Amsterdam), 1968, 38, 241-51. [all data]
Timmermans, 1935
Timmermans, J.,
Researches in Stoichiometry. I. The Heat of Fusion of Organic Compounds.,
Bull. Soc. Chim. Belg., 1935, 44, 17-40. [all data]
Clusius, 1929
Clusius, K.,
The specific heat of several condensed gases between 10deg. abs. and their triple point.,
Z. Phys. Chem., Abt. B, 1929, 3, 41. [all data]
Eucken and Karwat, 1924
Eucken, A.; Karwat, E.,
Determination of the heat content of several condensed gases,
Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1924, 112, 467. [all data]
Ambrose and Tsonopoulos, 1995
Ambrose, D.; Tsonopoulos, C.,
Vapor-Liquid Critical Properties of Elements and Compounds. 2. Normal Alkenes,
J. Chem. Eng. Data, 1995, 40, 531-546. [all data]
Younglove and Ely, 1987
Younglove, B.A.; Ely, J.F.,
Thermophysical Properties of Fluids II. Methane, Ethane, Propane, Isobutane, and Normal Butane,
J. Phys. Chem. Ref. Data, 1987, 16, 577. [all data]
Terry, Lynch, et al., 1969
Terry, M.J.; Lynch, J.T.; Bunclark, M.; Mansell, K.R.; Staveley, L.A.K.,
The Densities of Liquid Argon, Krypton, Xenon, Oxygen, Nitrogen, Carbon Monoxide, Methane and Carbon Tetrafluoride Along the Orthobaric Liquid Curve,
J. Chem. Thermodyn., 1969, 1, 413. [all data]
Vogt and Pitzer, 1976
Vogt, G.J.; Pitzer, K.S.,
Entropy and heat capacity of methane, spin-species conversion,
J. Chem. Thermodynam., 1976, 8, 1011-1031. [all data]
Frank and Clusius, 1937
Frank, A.; Clusius, K.,
The entropy of methane,
Z. Physik. Chem., 1937, B36, 291-300. [all data]
Stock, Henning, et al., 2006
Stock, Alfred; Henning, Fritz; Kuß, Ernst,
Dampfdrucktafeln für Temperaturbestimmungen zwischen + 25° und - 185°,
Ber. dtsch. Chem. Ges. A/B, 2006, 54, 5, 1119-1129, https://doi.org/10.1002/cber.19210540531
. [all data]
Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E.,
The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Ott, Goates, et al., 1972
Ott, J. Bevan; Goates, J. Rex; Lamb, John D.,
Solid-liquid phase equilibria in water + ethylene glycol,
The Journal of Chemical Thermodynamics, 1972, 4, 1, 123-126, https://doi.org/10.1016/S0021-9614(72)80015-6
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Reid, 1972
Reid, Robert C.,
Handbook on vapor pressure and heats of vaporization of hydrocarbons and related compounds, R. C. Wilhort and B. J. Zwolinski, Texas A Research Foundation. College Station, Texas(1971). 329 pages.$10.00,
AIChE J., 1972, 18, 6, 1278-1278, https://doi.org/10.1002/aic.690180637
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Ambrose, Counsell, et al., 1970
Ambrose, D.; Counsell, J.F.; Davenport, A.J.,
The use of Chebyshev polynomials for the representation of vapour pressures between the triple point and the critical point,
The Journal of Chemical Thermodynamics, 1970, 2, 2, 283-294, https://doi.org/10.1016/0021-9614(70)90093-5
. [all data]
Hestermans and White, 1961
Hestermans, P.; White, David,
THE VAPOR PRESSURE, HEAT OF VAPORIZATION AND HEAT CAPACITY OF METHANE FROM THE BOILING POINT TO THE CRITICAL TEMPERATURE,
J. Phys. Chem., 1961, 65, 2, 362-365, https://doi.org/10.1021/j100820a044
. [all data]
Frank and Clusius, 1939
Frank, A.; Clusius, K.,
Z. Phys. Chem. Abt. B, 1939, 42, 395. [all data]
Prydz and Goodwin, 1972
Prydz, R.; Goodwin, R.D.,
Experimental Melting and Vapor Pressures of Methane,
J. Chem. Thermodyn., 1972, 4, 1, 127-133, https://doi.org/10.1016/S0021-9614(72)80016-8
. [all data]
Regnier, 1972
Regnier, J.,
Tension de Vapeur de L'Ethane Entre 80 et 135 K,
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Cutler and Morrison, 1965
Cutler, A.J.B.; Morrison, J.A.,
Excess Thermodynamic Functions for Liquid Mixtures of Methane+Propane,
Trans. Faraday Soc., 1965, 61, 429-442, https://doi.org/10.1039/tf9656100429
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Bondi, 1963
Bondi, A.,
Heat of Siblimation of Molecular Crystals: A Catalog of Molecular Structure Increments.,
J. Chem. Eng. Data, 1963, 8, 3, 371-381, https://doi.org/10.1021/je60018a027
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Armstrong, Brickwedde, et al., 1955
Armstrong, George T.; Brickwedde, F.G.; Scott, R.B.,
Vapor pressures of the methanes,
J. RES. NATL. BUR. STAN., 1955, 55, 1, 39, https://doi.org/10.6028/jres.055.005
. [all data]
Jones, 1960
Jones, A.H.,
Sublimation Pressure Data for Organic Compounds.,
J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019
. [all data]
Tickner and Lossing, 1951
Tickner, A.W.; Lossing, F.P.,
The Measurement of Low Vapor Pressures by Means of a Mass Spectrometer.,
J. Phys. Chem., 1951, 55, 5, 733-740, https://doi.org/10.1021/j150488a013
. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References
- Symbols used in this document:
Cp,gas Constant pressure heat capacity of gas Pc Critical pressure Ptriple Triple point pressure S°gas Entropy of gas at standard conditions S°gas,1 bar Entropy of gas at standard conditions (1 bar) Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔcH°gas Enthalpy of combustion of gas at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization ΔvapS Entropy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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