Mercury, diethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas90. ± 50.kJ/molAVGN/AAverage of 6 values; Individual data points

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Mercury, diethyl- (l) + Mercury diiodide (cr) = 2C2H5HgI (cr)

By formula: C4H10Hg (l) + HgI2 (cr) = 2C2H5HgI (cr)

Quantity Value Units Method Reference Comment
Δr-55.2 ± 5.4kJ/molRSCHartley, Pritchard, et al., 1951Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Mercury, diethyl- (l) + Cl2Hg (cr) = 2Mercury, chloroethyl- (cr)

By formula: C4H10Hg (l) + Cl2Hg (cr) = 2C2H5ClHg (cr)

Quantity Value Units Method Reference Comment
Δr-87.7 ± 3.6kJ/molRSCHartley, Pritchard, et al., 1951Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Mercury, diethyl- (l) + Mercury(II) bromide (cr) = 2C2H5BrHg (cr)

By formula: C4H10Hg (l) + Br2Hg (cr) = 2C2H5BrHg (cr)

Quantity Value Units Method Reference Comment
Δr-74.5 ± 4.6kJ/molRSCHartley, Pritchard, et al., 1951Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hartley, Pritchard, et al., 1951
Hartley, K.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. IV. Mercury diethyl and mercury diphenyl, Trans. Faraday Soc., 1951, 47, 254, https://doi.org/10.1039/tf9514700254 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]


Notes

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