Phosphorus monoxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-5.629kcal/molReviewChase, 1998Data last reviewed in June, 1971
Quantity Value Units Method Reference Comment
gas,1 bar53.246cal/mol*KReviewChase, 1998Data last reviewed in June, 1971

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 600.600. to 6000.
A 5.8044018.563170
B 4.5087600.337912
C -0.363292-0.077108
D -1.7605010.007186
E 0.046368-0.227369
F -7.396901-8.836960
G 59.2173062.56730
H -5.628110-5.628110
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in June, 1971 Data last reviewed in June, 1971

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

(CAS Reg. No. 12359-19-2 • 4294967295Phosphorus monoxide) + Phosphorus monoxide = CAS Reg. No. 12359-19-2

By formula: (CAS Reg. No. 12359-19-2 • 4294967295OP) + OP = CAS Reg. No. 12359-19-2

Quantity Value Units Method Reference Comment
Δr165.4 ± 2.5kcal/molN/AN/Agas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

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