Methyl Alcohol

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Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, IR Spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
ΔfH°gas-49. ± 3.kcal/molAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
ΔcH°gas-182.52 ± 0.048kcal/molCmRossini, 1932Flame Calorimetry; Corresponding ΔfHºgas = -48.157 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
8.12650.Thermodynamics Research Center, 1997p=1 bar. Recommended entropies and heat capacities are in good agreement with other statistically calculated values [ Ivash E.V., 1955, Zhuravlev E.Z., 1959, Chen S.S., 1977, Chao J., 1986, Gurvich, Veyts, et al., 1989]. Please also see Chao J., 1986, 2.; GT
8.831100.
9.235150.
9.491200.
10.18273.15
10.53 ± 0.007298.15
10.56300.
12.34400.
14.27500.
16.06600.
17.65700.
19.06800.
20.30900.
21.401000.
22.361100.
23.211200.
23.9581300.
24.6131400.
25.1911500.
26.341750.
27.202000.
27.842250.
28.352500.
28.72750.
28.93000.

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
10.13 ± 0.30279.Stromsoe E., 1970Heat capacity at 279 K was obtained by thermal conductivity [ Halford J.O., 1957]. Vapor heat capacities from calorimetric measurements [ De Vries T., 1941] were converted to the ideal gas heat capacities by corrections for the gas imperfection effects [ Chen S.S., 1977, Chao J., 1986, 2]. Ideal gas heat capacities are given by [ Stromsoe E., 1970] as a linear function Cp=f1*(a+bT). This expression approximates the experimental values with the average deviation of 1.17 J/mol*K. The accuracy of the experimental heat capacities [ Stromsoe E., 1970] is estimated as less than 0.3%. Please also see De Vries T., 1941, Weltner W., 1951, Halford J.O., 1957.; GT
11.46 ± 0.30345.6
11.19 ± 0.28347.35
11.01 ± 0.30349.65
11.37 ± 0.28356.55
11.17 ± 0.30358.15
11.52 ± 0.30358.85
11.67 ± 0.30359.85
12.02 ± 0.30368.15
11.71 ± 0.28373.35
12.26 ± 0.30382.15
12.22 ± 0.28398.95
12.51 ± 0.30401.15
12.27 ± 0.28401.35
12.43 ± 0.10403.2
12.72 ± 0.30420.15
12.88 ± 0.28431.45
13.09 ± 0.28442.15
13.36 ± 0.30442.65
13.39 ± 0.28457.35
13.67 ± 0.10464.0
13.80 ± 0.28477.75
13.95 ± 0.28485.05
14.23 ± 0.28498.95
14.44 ± 0.30521.2
14.68 ± 0.28521.35
15.37 ± 0.28555.95
15.88 ± 0.28581.35
15.96 ± 0.28585.35

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, IR Spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Chlorine anion + Methyl Alcohol = (Chlorine anion • Methyl Alcohol)

By formula: Cl- + CH4O = (Cl- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°17. ± 3.kcal/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°22.6cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
ΔrS°24.1cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
ΔrS°22.0cal/mol*KPHPMSSieck, 1985gas phase; M
ΔrS°22.9cal/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
ΔrS°14.8cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrG°10.1 ± 0.8kcal/molAVGN/AAverage of 10 values; Individual data points

CH3O- + Hydrogen cation = Methyl Alcohol

By formula: CH3O- + H+ = CH4O

Quantity Value Units Method Reference Comment
ΔrH°382. ± 2.kcal/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrG°376.02 ± 0.62kcal/molH-TSNee, Osterwalder, et al., 2006gas phase; B
ΔrG°376.04 ± 0.55kcal/molH-TSOsborn, Leahy, et al., 1998gas phase; B
ΔrG°374.0 ± 2.0kcal/molIMREBartmess, Scott, et al., 1979gas phase; The acidity is 1.2 kcal/mol stronger than that from the D-EA cycle, due to the multi-compound fit for the acidity scale.; value altered from reference due to change in acidity scale; B
ΔrG°374.6 ± 2.1kcal/molH-TSHaas and Harrison, 1993gas phase; Both metastable and 50 eV collision energy.; B
ΔrG°375.10 ± 0.60kcal/molTDEqMeot-ner and Sieck, 1986gas phase; Experimental entropy: 21.5 eu, 0.6 less than H2O; B

CH5O+ + Methyl Alcohol = (CH5O+ • Methyl Alcohol)

By formula: CH5O+ + CH4O = (CH5O+ • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°32.6kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrH°32.3kcal/molPHPMSSzulejko and McMahon, 1992gas phase; M
ΔrH°32.1kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; M
ΔrH°33.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
ΔrH°33.7kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°29.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrS°29.2cal/mol*KPHPMSSzulejko and McMahon, 1992gas phase; M
ΔrS°26.6cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; M
ΔrS°30.5cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M
ΔrS°28.5cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°25.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

CH3O- + Methyl Alcohol = (CH3O- • Methyl Alcohol)

By formula: CH3O- + CH4O = (CH3O- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°29.3 ± 1.0kcal/molTDAsPaul and Kebarle, 1990gas phase; B,M
ΔrH°28.80 ± 0.30kcal/molTDAsMeot-ner and Sieck, 1986gas phase; B,M
ΔrH°29.4 ± 2.5kcal/molTDAsCaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
ΔrH°19.0 ± 2.0kcal/molN/AMoylan, Dodd, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°31.8cal/mol*KPHPMSPaul and Kebarle, 1990gas phase; M
ΔrS°26.7cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrG°20.30kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
ΔrG°19.8 ± 1.0kcal/molTDAsPaul and Kebarle, 1990gas phase; B
ΔrG°20.80 ± 0.50kcal/molTDAsMeot-ner and Sieck, 1986gas phase; B
ΔrG°20.3 ± 1.6kcal/molTDAsCaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
19.1296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(CH3O-)H2O; Meot-Ner(Mautner), 1986; M

C4H9O- + Methyl Alcohol = (C4H9O- • Methyl Alcohol)

By formula: C4H9O- + CH4O = (C4H9O- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°25.5 ± 1.0kcal/molTDEqMeot-Ner and Sieck, 1986gas phase; B,M
ΔrH°23.4 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
ΔrH°26.0 ± 2.5kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M
Quantity Value Units Method Reference Comment
ΔrS°27.9cal/mol*KN/AMeot-Ner and Sieck, 1986gas phase; Entropy change calculated or estimated; M
ΔrS°29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
ΔrG°10.20kcal/molIMREMustanir, Matsuoka, et al., 2006gas phase; B
ΔrG°17.1 ± 1.6kcal/molTDEqMeot-Ner and Sieck, 1986gas phase; B
ΔrG°17.3 ± 1.6kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M

C2H5O- + Methyl Alcohol = (C2H5O- • Methyl Alcohol)

By formula: C2H5O- + CH4O = (C2H5O- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°27.3 ± 2.9kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
ΔrH°25.6 ± 1.9kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
Quantity Value Units Method Reference Comment
ΔrS°29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
ΔrG°18.6 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
13.4296.FAMackay, Rakshit, et al., 1982gas phase; From thermochemical cycle,switching reaction(CH3O-)CH3OH; Caldwell and Kebarle, 1986, Taft, 1983; M

(Chlorine anion • Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 2Methyl Alcohol)

By formula: (Cl- • CH4O) + CH4O = (Cl- • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°14.10 ± 0.40kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°13.70 ± 0.20kcal/molTDAsEvans and Keesee, 1991gas phase; B,M
ΔrH°14.1 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
ΔrH°13.00 ± 0.70kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°24.2cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
ΔrS°22.0cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
ΔrS°19.4cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°7.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°7.10kcal/molTDAsEvans and Keesee, 1991gas phase; B
ΔrG°6.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
ΔrG°7.20 ± 0.40kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 2Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 3Methyl Alcohol)

By formula: (Cl- • 2CH4O) + CH4O = (Cl- • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°11.50 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°10.80 ± 0.30kcal/molTDAsEvans and Keesee, 1991gas phase; B,M
ΔrH°11.8 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
ΔrH°12.30 ± 0.60kcal/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
ΔrS°22.7cal/mol*KHPMSEvans and Keesee, 1991gas phase; M
ΔrS°23.6cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.06kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°4.00kcal/molTDAsEvans and Keesee, 1991gas phase; B
ΔrG°4.9 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
ΔrG°5.20 ± 0.30kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

C8H5- + Methyl Alcohol = (C8H5- • Methyl Alcohol)

By formula: C8H5- + CH4O = (C8H5- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°21.5 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; B
ΔrH°21.4 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity Value Units Method Reference Comment
ΔrS°29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
ΔrG°11.0 ± 2.0kcal/molIMREChabinyc and Brauman, 1999gas phase; B
ΔrG°12.7 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

CN- + Methyl Alcohol = (CN- • Methyl Alcohol)

By formula: CN- + CH4O = (CN- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°15.70 ± 0.80kcal/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
ΔrH°16.6 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
ΔrH°16.5 ± 3.5kcal/molIMRELarson and McMahon, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°23.cal/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
ΔrS°24.3cal/mol*KN/ALarson and McMahon, 1987gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity Value Units Method Reference Comment
ΔrG°8.80 ± 0.20kcal/molTDAsLarson, Szulejko, et al., 1988gas phase; B
ΔrG°10.4 ± 1.0kcal/molTDAsMeot-ner, 1988gas phase; B
ΔrG°9.2 ± 2.3kcal/molIMRELarson and McMahon, 1987gas phase; B,M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) • Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°36.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°38.1kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
ΔrH°38.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°26.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
ΔrG°30.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Iodide + Methyl Alcohol = (Iodide • Methyl Alcohol)

By formula: I- + CH4O = (I- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°11.90 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°11.3 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B,M
ΔrH°11.2kcal/molPHPMSHiraoka and Yamabe, 1991gas phase; M
ΔrH°11.kcal/molPHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°17.1cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
ΔrS°17.8cal/mol*KPHPMSCaldwell and Kebarle, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.76kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°6.0 ± 1.0kcal/molTDAsCaldwell and Kebarle, 1984gas phase; B
ΔrG°5.7 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

C2H5O+ + Methyl Alcohol = (C2H5O+ • Methyl Alcohol)

By formula: C2H5O+ + CH4O = (C2H5O+ • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°30.3kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°26.9cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°22.3kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C2H7O+ + Methyl Alcohol = (C2H7O+ • Methyl Alcohol)

By formula: C2H7O+ + CH4O = (C2H7O+ • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°29.6kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°26.6cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°21.7kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C3H7O- + Methyl Alcohol = (C3H7O- • Methyl Alcohol)

By formula: C3H7O- + CH4O = (C3H7O- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°26.9 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity Value Units Method Reference Comment
ΔrS°29.3cal/mol*KN/ACaldwell, Rozeboom, et al., 1984gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity Value Units Method Reference Comment
ΔrG°18.2 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

Fluorine anion + Methyl Alcohol = (Fluorine anion • Methyl Alcohol)

By formula: F- + CH4O = (F- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°29.6 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
ΔrH°29.4 ± 2.2kcal/molCIDTDeTuri and Ervin, 1999gas phase; B
ΔrH°23.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.0cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
ΔrS°22.6cal/mol*KN/ALarson and McMahon, 1983gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity Value Units Method Reference Comment
ΔrG°22.8 ± 2.0kcal/molIMRELarson and McMahon, 1983gas phase; B,M
ΔrG°15.8 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Chlorine anion • 3Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 4Methyl Alcohol)

By formula: (Cl- • 3CH4O) + CH4O = (Cl- • 4CH4O)

Quantity Value Units Method Reference Comment
ΔrH°10.5 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
ΔrH°10.50kcal/molTDAsEvans and Keesee, 1991gas phase; B
ΔrH°11.20 ± 0.60kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.9cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
ΔrS°26.4cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3.6 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
ΔrG°3.70kcal/molTDAsEvans and Keesee, 1991gas phase; B
ΔrG°3.30 ± 0.20kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

Bromine anion + Methyl Alcohol = (Bromine anion • Methyl Alcohol)

By formula: Br- + CH4O = (Br- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°14.50 ± 0.10kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°13.9 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°17.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8.00 ± 0.10kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°8.7 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B
ΔrG°8.4 ± 2.0kcal/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

C3H9Si+ + Methyl Alcohol = (C3H9Si+ • Methyl Alcohol)

By formula: C3H9Si+ + CH4O = (C3H9Si+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°39.2kcal/molPHPMSWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°29.7cal/mol*KN/AWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
25.3468.PHPMSWojtyniak and Stone, 1986gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

Sodium ion (1+) + Methyl Alcohol = (Sodium ion (1+) • Methyl Alcohol)

By formula: Na+ + CH4O = (Na+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°23.2 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.9 ± 1.4kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°24.0 ± 0.2kcal/molHPMSHoyau, Norrman, et al., 1999RCD
ΔrH°26.6 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°20500.cal/mol*KHPMSHoyau, Norrman, et al., 1999RCD
ΔrS°24.3cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.3298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

(Chlorine anion • 4Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 5Methyl Alcohol)

By formula: (Cl- • 4CH4O) + CH4O = (Cl- • 5CH4O)

Quantity Value Units Method Reference Comment
ΔrH°9.2 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
ΔrH°10.50 ± 0.50kcal/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°21.7cal/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
ΔrS°25.5cal/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°2.7 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; B
ΔrG°2.90 ± 0.10kcal/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

Water + Propane, 2,2-dimethoxy- = 2Methyl Alcohol + Acetone

By formula: H2O + C5H12O2 = 2CH4O + C3H6O

Quantity Value Units Method Reference Comment
ΔrH°4.86 ± 0.01kcal/molCmWiberg, Morgan, et al., 1994liquid phase; ALS
ΔrH°4.88 ± 0.01kcal/molCmWiberg and Squires, 1979liquid phase; Heat of hydrolysis; ALS
ΔrH°4.8836 ± 0.0067kcal/molCmWiberg and Squires, 1979, 2liquid phase; solvent: Water; Hydrolysis; ALS
ΔrH°-3.95 ± 0.05kcal/molCmStern and Dorer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 3.69 ± 0.05 kcal/mol; Heat of hydrolysis; ALS

(CH5O+ • Methyl Alcohol) + Methyl Alcohol = (CH5O+ • 2Methyl Alcohol)

By formula: (CH5O+ • CH4O) + CH4O = (CH5O+ • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°21.2kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrH°21.0kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; M
ΔrH°21.3kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrS°25.8cal/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; M
ΔrS°28.2cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

C5H11O- + Methyl Alcohol = (C5H11O- • Methyl Alcohol)

By formula: C5H11O- + CH4O = (C5H11O- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°25.7 ± 2.9kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
ΔrG°17.0 ± 2.0kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

C6H11S2- + Methyl Alcohol = (C6H11S2- • Methyl Alcohol)

By formula: C6H11S2- + CH4O = (C6H11S2- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°21.9 ± 2.5kcal/molN/ACaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity Value Units Method Reference Comment
ΔrG°13.2 ± 1.6kcal/molIMRECaldwell, Rozeboom, et al., 1984gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

(Copper ion (1+) • Methyl Alcohol) + Methyl Alcohol = (Copper ion (1+) • 2Methyl Alcohol)

By formula: (Cu+ • CH4O) + CH4O = (Cu+ • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°13.8kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
ΔrG°6.3kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

(CH5O+ • 2Water • 3Methyl Alcohol) + Water = (CH5O+ • 3Water • 3Methyl Alcohol)

By formula: (CH5O+ • 2H2O • 3CH4O) + H2O = (CH5O+ • 3H2O • 3CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°9.1kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°22.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.1272.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ • 3Water • 2Methyl Alcohol) + Water = (CH5O+ • 4Water • 2Methyl Alcohol)

By formula: (CH5O+ • 3H2O • 2CH4O) + H2O = (CH5O+ • 4H2O • 2CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°9.3kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°22.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.2272.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ • 4Water • Methyl Alcohol) + Water = (CH5O+ • 5Water • Methyl Alcohol)

By formula: (CH5O+ • 4H2O • CH4O) + H2O = (CH5O+ • 5H2O • CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°9.4kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°22.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.5269.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ • Water) + Methyl Alcohol = (CH5O+ • Methyl Alcohol • Water)

By formula: (CH5O+ • H2O) + CH4O = (CH5O+ • CH4O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°24.5kcal/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°29.cal/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
11.6452.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

C6H5NO2- + Methyl Alcohol = (C6H5NO2- • Methyl Alcohol)

By formula: C6H5NO2- + CH4O = (C6H5NO2- • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°15.10 ± 0.20kcal/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°26.1cal/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°7.30 ± 0.40kcal/molTDAsSieck, 1985gas phase; B
ΔrG°6.3 ± 1.6kcal/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.3343.PHPMSChowdhury, 1987gas phase; M

Copper ion (1+) + Methyl Alcohol = (Copper ion (1+) • Methyl Alcohol)

By formula: Cu+ + CH4O = (Cu+ • CH4O)

Quantity Value Units Method Reference Comment
ΔrH°13.4kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/AEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity Value Units Method Reference Comment
ΔrG°5.9kcal/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

(Fluorine anion • Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 2Methyl Alcohol)

By formula: (F- • CH4O) + CH4O = (F- • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°20.30 ± 0.30kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°19.3 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°23.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°12.97kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°12.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Fluorine anion • 2Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 3Methyl Alcohol)

By formula: (F- • 2CH4O) + CH4O = (F- • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°15.10 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°14.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°21.2cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°8.06kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°8.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion • 2Methyl Alcohol) + Methyl Alcohol = (Bromine anion • 3Methyl Alcohol)

By formula: (Br- • 2CH4O) + CH4O = (Br- • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°9.50 ± 0.50kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°10.6 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°21.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°4.25kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°4.2 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Bromine anion • Methyl Alcohol) + Methyl Alcohol = (Bromine anion • 2Methyl Alcohol)

By formula: (Br- • CH4O) + CH4O = (Br- • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°12.00 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°12.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°20.7cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°5.62kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°6.3 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide • 2Methyl Alcohol) + Methyl Alcohol = (Iodide • 3Methyl Alcohol)

By formula: (I- • 2CH4O) + CH4O = (I- • 3CH4O)

Quantity Value Units Method Reference Comment
ΔrH°7.70 ± 0.60kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°9.8 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.4cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°3.41kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°3.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Iodide • Methyl Alcohol) + Methyl Alcohol = (Iodide • 2Methyl Alcohol)

By formula: (I- • CH4O) + CH4O = (I- • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°9.50 ± 0.20kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrH°11.1 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°22.6cal/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°4.25kcal/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
ΔrG°4.4 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; B

(Chlorine anion • 10Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 11Methyl Alcohol)

By formula: (Cl- • 10CH4O) + CH4O = (Cl- • 11CH4O)

Quantity Value Units Method Reference Comment
ΔrH°7.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
ΔrS°20.cal/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°1.3 ± 1.0kcal/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Sodium ion (1+) • Methyl Alcohol) + Methyl Alcohol = (Sodium ion (1+) • 2Methyl Alcohol)

By formula: (Na+ • CH4O) + CH4O = (Na+ • 2CH4O)

Quantity Value Units Method Reference Comment
ΔrH°20.5 ± 1.4kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.4 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°20.5 ± 1.6kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°20.2 ± 0.2kcal/molHPMSGuo, Conklin, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°21.7cal/mol*KHPMSGuo, Conklin, et al., 1989gas phase; M

H4ClO2- + Methyl Alcohol + 2Water = CH8ClO3-

By formula: H4ClO2- + CH4O + 2H2O = CH8ClO3-

Quantity Value Units Method Reference Comment
ΔrH°10.40 ± 0.20kcal/molTDAsEvans and Keesee, 1991gas phase; B
ΔrH°11.40 ± 0.30kcal/molTDAsEvans and Keesee, 1991gas phase; For solvation by MeOH of core ion; B
Quantity Value Units Method Reference Comment
ΔrG°5.80kcal/molTDAsEvans and Keesee, 1991gas phase; B
ΔrG°6.00kcal/molTDAsEvans and Keesee, 1991gas phase; For solvation by MeOH of core ion; B

(CH5O+ • 2Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (CH5O+ • 2CH4O) + C2H6O = (CH5O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°17.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°28.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 3Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (CH5O+ • 3CH4O) + C2H6O = (CH5O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°13.7kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°30.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 2Methyl Alcohol) + Methyl Alcohol = (CH5O+ • 3Methyl Alcohol)

By formula: (CH5O+ • 2CH4O) + CH4O = (CH5O+ • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°14.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrH°16.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°24.0cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrS°28.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ • 3Methyl Alcohol) + Methyl Alcohol = (CH5O+ • 4Methyl Alcohol)

By formula: (CH5O+ • 3CH4O) + CH4O = (CH5O+ • 4CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°11.3kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrH°13.5kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°22.3cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrS°28.7cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ • 4Methyl Alcohol) + Methyl Alcohol = (CH5O+ • 5Methyl Alcohol)

By formula: (CH5O+ • 4CH4O) + CH4O = (CH5O+ • 5CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°10.2kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrH°12.5kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°23.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrS°31.1cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ • Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • Methyl Alcohol)

By formula: (CH5O+ • CH4O) + C2H6O = (CH5O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°21.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°25.2cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 5Methyl Alcohol) + Methyl Alcohol = (CH5O+ • 6Methyl Alcohol)

By formula: (CH5O+ • 5CH4O) + CH4O = (CH5O+ • 6CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°9.3kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrH°11.9kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°23.5cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrS°32.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(CH5O+ • 6Methyl Alcohol) + Methyl Alcohol = (CH5O+ • 7Methyl Alcohol)

By formula: (CH5O+ • 6CH4O) + CH4O = (CH5O+ • 7CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°9.0kcal/molPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrH°12.0kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°25.7cal/mol*KPHPMSMeot-Ner (Mautner), 1992gas phase; M
ΔrS°35.7cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(Fluorine anion • 11Methyl Alcohol) + Methyl Alcohol = (Fluorine anion • 12Methyl Alcohol)

By formula: (F- • 11CH4O) + CH4O = (F- • 12CH4O)

Quantity Value Units Method Reference Comment
ΔrH°8.5 ± 1.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B,M
Quantity Value Units Method Reference Comment
ΔrS°25.cal/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrG°1.1 ± 2.0kcal/molTDAsHiraoka and Yamabe, 1991gas phase; Entropy estimated.; B

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas Chromatography, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson

Data compiled by: Pamela M. Chu, Franklin R. Guenther, George C. Rhoderick, and Walter J. Lafferty

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillarySE-30140.340.Haken and Korhonen, 1985Column length: 25. m; Column diameter: 0.33 mm
PackedSE-30100.384.Winskowski, 1983Gaschrom Q; Column length: 2. m
PackedSE-30150.356.Haken, Nguyen, et al., 1979Celatom AW silanized; Column length: 3.7 m
PackedApiezon L120.336.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedSE-30100.373.Pías and Gascó, 1975Ar, Chromosorb W AW DMCS HP (80-100 mesh); Column length: 1. m
PackedApiezon L100.355.Brown, Chapman, et al., 1968N2, DCMS-treated Chromosorb W; Column length: 2.3 m
PackedSE-3080.330.Viani, Müggler-Chavan, et al., 1965He, Chromosorb P; Column length: 6. m

Kovats' RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryPetrocol DH-100380.Haagen-Smit Laboratory, 1997He; Column length: 100. m; Column diameter: 0.2 mm; Program: 5C(10min) => 5C/min => 50C(48min) => 1.5C/min => 195C(91min)

Kovats' RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-351100.917.Haken and Korhonen, 1985N2; Column length: 25. m; Column diameter: 0.32 mm
CapillaryOV-35180.891.Haken and Korhonen, 1985N2; Column length: 25. m; Column diameter: 0.32 mm
PackedPEG-2000152.860.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPEG-2000179.881.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedCarbowax 20M100.892.Zarazir, Chovin, et al., 1970Chromosorb W; Column length: 2. m
PackedPolyethylene Glycol 4000100.904.Bonastre and Grenier, 1968Chromosorb P; Column length: 6. m
PackedPolyethylene Glycol 4000120.897.Bonastre and Grenier, 1968Chromosorb P; Column length: 6. m
PackedPolyethylene Glycol 4000140.886.Bonastre and Grenier, 1968Chromosorb P; Column length: 6. m
PackedPolyethylene Glycol 400080.914.Bonastre and Grenier, 1968Chromosorb P; Column length: 6. m

Kovats' RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryCBP-20899.Shimadzu, 200325. m/0.2 mm/0.25 μm, He, 50. C @ 5. min, 4. K/min; Tend: 200. C
CapillaryDB-Wax888.Shimoda and Shibamoto, 1990He, 40. C @ 6. min, 3. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 190. C

Kovats' RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
PackedCarbowax 20M869.Kevei and Kozma, 1976Chromosorb; Program: not specified

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryPetrocol DH372.7Censullo, Jones, et al., 200350. m/0.25 mm/0.5 μm, He, 35. C @ 10. min, 3. K/min, 200. C @ 10. min
CapillaryPetrocol DH378.2Censullo, Jones, et al., 200350. m/0.25 mm/0.5 μm, He, 35. C @ 10. min, 3. K/min, 200. C @ 10. min
CapillarySE-30400.0Golovnya, Kuz'menko, et al., 200025. m/0.32 mm/1. μm, He, 4. K/min; Tstart: 60. C
CapillarySE-30400.0Golovnya, Kuz'menko, et al., 2000, 225. m/0.32 mm/1. μm, He, 4. K/min; Tstart: 60. C
CapillaryDB-1361.Bartelt, 199730. m/0.32 mm/5. μm, He, 35. C @ 1. min, 10. K/min; Tend: 270. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
PackedSE-30368.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Van Den Dool and Kratz RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryCarbowax910.4Censullo, Jones, et al., 200360. m/0.25 mm/0.5 μm, He, 50. C @ 10. min, 5. K/min, 250. C @ 10. min
CapillaryFFAP916.Ott, Fay, et al., 199730. m/0.25 mm/0.25 μm, He, 20. C @ 1. min, 4. K/min, 200. C @ 1. min
PackedCarbowax 20M866.van den Dool and Kratz, 1963Celite 545, 4.6 K/min; Tstart: 75. C; Tend: 228. C

Normal alkane RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryDB-160.382.Shimadzu, 2003, 260. m/0.32 mm/1. μm, He
PackedSqualane100.338.Vernon, 1971N2
PackedDC-400150.370.Anderson, 1968Helium, Gas-Pak (60-80 mesh); Column length: 3.0 m
PackedSqualane125.348.Cremer and Nonn, 1964H2, Chromosorb W (80-100 mesh); Column length: 3. m

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxane: CP-Sil 5 CB395.Bramston-Cook, 201360. m/0.25 mm/1.0 μm, Helium, 45. C @ 1.45 min, 3.6 K/min, 210. C @ 2.72 min
CapillaryPetrocol DH379.Supelco, 2012100. m/0.25 mm/0.50 μm, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min
CapillaryHP-5367.5Leffingwell and Alford, 200560. m/0.32 mm/0.25 μm, He, 30. C @ 2. min, 2. K/min, 260. C @ 28. min
CapillaryOV-101381.Zenkevich, 200525. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C
CapillaryBP-1370.Health Safety Executive, 200050. m/0.22 mm/0.75 μm, He, 5. K/min; Tstart: 50. C; Tend: 200. C
CapillaryDB-5MS353.5Shoenmakers, Oomen, et al., 200030. m/0.25 mm/0.25 μm, He, 40. C @ 1. min, 3. K/min; Tend: 250. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-5 MS381.Kotowska, Zalikowski, et al., 201230. m/0.25 mm/0.25 μm, Helium; Program: not specified
CapillaryMethyl Silicone373.Chen and Feng, 2007Program: not specified
CapillaryMethyl Silicone373.Kou, Zhang, et al., 2006Program: not specified
CapillaryMethyl Silicone408.Blunden, Aneja, et al., 200560. m/0.32 mm/1.0 μm, Helium; Program: -50 0C (2 min) 8 0C/min -> 200 0C (7.75 min) 25 0C -> 225 0C (8 min)
CapillaryMethyl Silicone373.Fu and Wang, 2004Program: not specified
CapillaryMethyl Silicone362.N/AProgram: not specified
CapillaryPolydimethyl siloxanes381.Zenkevich, 2001Program: not specified
CapillaryPolydimethyl siloxanes381.Zenkevich, 2001, 2Program: not specified
CapillaryMethyl Silicone381.Zenkevich, 1999Program: not specified
CapillarySPB-1353.Flanagan, Streete, et al., 199760. m/0.53 mm/5. μm, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillaryPolydimethyl siloxanes381.Zenkevich and Chupalov, 1996Program: not specified
CapillaryMethyl Silicone381.Zenkevich, Korolenko, et al., 1995Program: not specified
CapillaryDB-1348.Schuberth, 199430. m/0.25 mm/1. μm, He; Program: 40C (4min) => 10C/min => 200C => 50C/min => 250C
CapillarySPB-1353.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
CapillarySPB-1391.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: not specified
CapillaryCP Sil 8 CB404.Weller and Wolf, 198940. m/0.25 mm/0.25 μm, He; Program: 30 0C (1 min) 15 0C/min -> 45 0C 3 0C/min -> 120 0C
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.384.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified

Normal alkane RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M100.892.Sun, Siepmann, et al., 200630. m/0.25 mm/0.25 μm, Helium
CapillaryCarbowax 20M60.899.Sun, Siepmann, et al., 200630. m/0.25 mm/0.25 μm, Helium
CapillaryCarbowax 20M80.895.Sun, Siepmann, et al., 200630. m/0.25 mm/0.25 μm, Helium
CapillaryDB-Wax60.921.Shimadzu, 2003, 250. m/0.32 mm/1. μm, He

Normal alkane RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-Wax911.Shimadzu, 201230. m/0.32 mm/0.50 μm, Helium, 4. K/min; Tstart: 40. C; Tend: 260. C
CapillaryDB-Wax907.Chida, Sone, et al., 200460. m/0.25 mm/0.5 μm, 35. C @ 5. min, 4. K/min, 240. C @ 10. min
CapillaryDB-Wax911.Shimadzu Corporation, 200330. m/0.32 mm/0.5 μm, He, 4. K/min; Tstart: 40. C; Tend: 260. C
CapillaryDB-Wax903.Tanaka, Yamauchi, et al., 200330. m/0.25 mm/0.25 μm, 30. C @ 1. min, 4. K/min; Tend: 250. C
CapillaryDB-Wax905.Tanaka, Yamauchi, et al., 200330. m/0.25 mm/0.25 μm, 30. C @ 1. min, 4. K/min; Tend: 250. C
CapillaryTC-Wax898.Suhardi, Suzuki, et al., 200260. m/0.25 mm/0.25 μm, He, 40. C @ 10. min, 3. K/min, 230. C @ 10. min
CapillaryDB-Wax905.Duque, Bonilla, et al., 200130. m/0.25 mm/0.25 μm, Helium, 4. K/min, 220. C @ 30. min; Tstart: 25. C

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryCarbowax 20M920.Vinogradov, 2004Program: not specified
CapillaryPolyethylene Glycol897.Zenkevich, Korolenko, et al., 1995Program: not specified
CapillaryDB-Wax909.Peng, Yang, et al., 1991Program: not specified
CapillaryCarbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.907.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryCarbowax 400, Carbowax 20M, Carbowax 1540, Carbowax 4000, Superox 06, PEG 20M, etc.920.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryCarbowax 20M883.Ramsey and Flanagan, 1982Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, IR Spectrum, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rossini, 1932
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Ivash E.V., 1955
Ivash E.V., Thermodynamic properties of ideal gaseous methanol, J. Chem. Phys., 1955, 23, 1814-1818. [all data]

Zhuravlev E.Z., 1959
Zhuravlev E.Z., Isotopic effect on thermodynamic functions of some organic deuterocompounds in the ideal gas state, Tr. Khim. i Khim. Tekhnol., 1959, 2, 475-485. [all data]

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Gurvich, L.V.; Veyts, I.V.; Alcock, C.B., Thermodynamic Properties of Individual Substances, 4th ed.; Vols. 1 and 2, Hemisphere, New York, 1989. [all data]

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Halford J.O., 1957
Halford J.O., Standard heat capacities of gaseous methanol, ethanol, methane and ethane at 279 K by thermal conductivity, J. Phys. Chem., 1957, 61, 1536-1539. [all data]

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Weltner W., 1951
Weltner W., Jr., Methyl alcohol: the entropy, heat capacity and polymerization equilibria in the vapor, and potential barrier to internal rotation, J. Am. Chem. Soc., 1951, 73, 2606-2610. [all data]

Evans and Keesee, 1991
Evans, D.H.; Keesee, R.G., Thermodynamics of Gas-Phase Mixed-Solvent Cluster Ions - Water and Methanol on K+ and Cl- and Comparison to Liquid Solutions, J. Phys. Chem., 1991, 95, 9, 3558, https://doi.org/10.1021/j100162a024 . [all data]

Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S., Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH, Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4 . [all data]

Sieck, 1985
Sieck, L.W., Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure., J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049 . [all data]

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Yamdagni, Payzant, et al., 1973
Yamdagni, R.; Payzant, J.D.; Kebarle, P., Solvation of Cl- and O2- with H2O, CH3OH, and CH3CN in the gas phase, Can. J. Chem., 1973, 51, 2507. [all data]

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Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Solvation of the Hydrogen Ion by Methanol, Dimethyl Ether and Water. Effect of Hydrogen Bonding, J. Am. Chem. Soc., 1973, 95, 24, 7939, https://doi.org/10.1021/ja00805a002 . [all data]

Larson and McMahon, 1982
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MacKay, G.I.; Bohme, D.K., Proton-Transfer Reactions in Nitromethane at 297K, Int. J. Mass Spectrom. Ion Phys., 1978, 26, 4, 327, https://doi.org/10.1016/0020-7381(78)80052-7 . [all data]

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Larson, J.W.; McMahon, T.B., Hydrogen bonding in gas phase anions. The energetics of interaction between cyanide ion and bronsted acids, J. Am. Chem. Soc., 1987, 109, 6230. [all data]

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Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

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Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

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Staley, R.H.; Beauchamp, J.L., Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases, J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050 . [all data]

Caldwell and Kebarle, 1984
Caldwell, G.; Kebarle, P., Binding energies and structural effects in halide anion-ROH and -RCOOH complexes from gas phase equilibria measurements, J. Am. Chem. Soc., 1984, 106, 967. [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Solvation of Halide Ions with CH3OH in the gas Phase, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 133, https://doi.org/10.1016/0168-1176(91)85101-Q . [all data]

Caldwell, Masucci, et al., 1989
Caldwell, G.W.; Masucci, J.A.; Ikonomou, M.G., Negative Ion Chemical Ionization Mass Spectrometry - Binding of Molecules to Bromide and Iodide Anions, Org. Mass Spectrom., 1989, 24, 1, 8, https://doi.org/10.1002/oms.1210240103 . [all data]

Tanabe, Morgon, et al., 1996
Tanabe, F.K.J.; Morgon, N.H.; Riveros, J.M., Relative Bromide and Iodide Affinity of Simple Solvent Molecules Determined by FT-ICR, J. Phys. Chem., 1996, 100, 8, 2862-2866, https://doi.org/10.1021/jp952290p . [all data]

Larson and McMahon, 1983
Larson, J.W.; McMahon, T.B., Strong hydrogen bonding in gas-phase anions. An ion cyclotron resonance determination of fluoride binding energetics to bronsted acids from gas-phase fluoride exchange equilibria measurements, J. Am. Chem. Soc., 1983, 105, 2944. [all data]

Arshadi, Yamdagni, et al., 1970
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Notes

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