Silane, ethenyltrimethyl-
- Formula: C5H12Si
- Molecular weight: 100.2343
- IUPAC Standard InChI: InChI=1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3
- IUPAC Standard InChIKey: GCSJLQSCSDMKTP-UHFFFAOYSA-N
- CAS Registry Number: 754-05-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Silane, trimethylvinyl-; (Trimethylsilyl)ethylene; Trimethylvinylsilane; Vinyltrimethylsilane; CH2=CHSi(CH3)3; Vinyltrimethysilane
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| S°liquid | 74.62 | cal/mol*K | N/A | Lebedev, Lebedev, et al., 1981 | |
| S°liquid | 74.90 | cal/mol*K | N/A | Rabinovich, Lebedev, et al., 1975 |
Constant pressure heat capacity of liquid
| Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 47.32 | 298.15 | Lebedev, Lebedev, et al., 1981 | T = 5 to 330 K. |
| 47.39 | 300. | Rabinovich, Lebedev, et al., 1975 | T = 50 to 300 K. |
IR Spectrum
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Data compiled by: Coblentz Society, Inc.
- SOLUTION (10% CCl4 FOR 3800-1335, 10% CS2 FOR 1335-450 CM-1); DOW KBr FOREPRISM-GRATING; DIGITIZED BY COBLENTZ SOCIETY (BATCH I) FROM HARD COPY; 2 cm-1 resolution
- SOLUTION (10% IN CCl4 FOR 3800-1000, 5% IN CS2 FOR 1300-400, AND 10% IN CCl4 FOR 600-210 CM-1); PERKIN-ELMER 521 (GRATING); DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 2 cm-1 resolution
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | OV-101 | 60. | 537. | Blazsó and Garzó, 1974 | Column length: 20. m |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-101 | 550. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
References
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lebedev, Lebedev, et al., 1981
Lebedev, B.V.; Lebedev, N.K.; Khotimskii, V.S.; Durgar'yan, S.G.; Nametkin, N.S.,
Thermodynamics of polymerization of vinylorganosilanes,
Dokl. Akad. Nauk, 1981, SSSR 259, 629-633. [all data]
Rabinovich, Lebedev, et al., 1975
Rabinovich, I.B.; Lebedev, B.V.; Tsvetkova, L.Ya.; Nametkin, N.S.; Durgar'yan, S.G.; Khotimskii, V.S.; Kiparisova, Y.G.,
Thermodynamics of polymerization of vinyltrimethylsilane,
Vysokomol. Soedin., 1975, A17, 1421-1425. [all data]
Blazsó and Garzó, 1974
Blazsó, M.; Garzó, G.,
Identification of Isomeric Structures of Phenyl and Trimethylsilyl Substituted 1-Alkenes by Gas Chromatography,
Chromatographia, 1974, 7, 8, 395-398, https://doi.org/10.1007/BF02330942
. [all data]
Zenkevich, 2005
Zenkevich, I.G.,
Experimentally measured retention indices., 2005. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Gas Chromatography, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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