Lead, tetramethyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid98.1 ± 4.4kJ/molReviewMartinho SimõesSelected data; MS
Δfliquid129.6 ± 3.3kJ/molReviewMartinho SimõesMS
Δfliquid-25. ± 13.kJ/molReviewMartinho SimõesThe enthalpy of formation of Pb(Me)4(l) is calculated as -3. ± 13. kJ/mol by assuming that PbO(cr, yellow) is the product oxide.; MS
Quantity Value Units Method Reference Comment
Δcliquid-3711.2 ± 1.3kJ/molCC-RBGood, Scott, et al., 1959Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Δcliquid-3636.7 ± 3.2kJ/molCC-SBChlupacek, 1953MS
Δcliquid-3505. ± 13.kJ/molCC-SBLippincott and Tobin, 1953MS
Quantity Value Units Method Reference Comment
liquid319.99J/mol*KN/AGood, Scott, et al., 1959, 2DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
202.5298.15Good, Scott, et al., 1959, 2DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Good, Scott, et al., 1959
Good, W.D.; Scott, D.W.; Lacina, J.L.; McCullough, J.P., J. Phys. Chem., 1959, 63, 1139. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Chlupacek, 1953
Chlupacek, W., Chem. Tech., 1953, art 8. [all data]

Lippincott and Tobin, 1953
Lippincott, E.R.; Tobin, M.C., J. Am. Chem. Soc., 1953, 75, 4141. [all data]

Good, Scott, et al., 1959, 2
Good, W.D.; Scott, D.W.; Lacina, J.L.; McCullough, J.P., Tetramethyllead: heat of formation by rotating-bomb calorimetry, J. Phys. Chem., 1959, 63, 1139-1142. [all data]


Notes

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