Hydrazine, 1,2-dimethyl-
- Formula: C2H8N2
- Molecular weight: 60.0983
- IUPAC Standard InChIKey: DIIIISSCIXVANO-UHFFFAOYSA-N
- CAS Registry Number: 540-73-8
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: s-Dimethylhydrazine; DMH; Hydrazomethane; N,N'-Dimethylhydrazine; SDMH; 1,2-Dimethylhydrazine; (CH3NH)2; 1,2-Dimethylhydrazin; sym-Dimethylhydrazine; Dimethylhydrazine, symmetrical; Rcra waste number U099; Symetryczna dwumetylohydrazyna; UN 2382
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Condensed phase thermochemistry data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔcH°liquid | -1983.0 ± 4.2 | kJ/mol | Ccb | Aston, Rock, et al., 1952 | Reanalyzed by Cox and Pilcher, 1970, Original value = -1980.93 kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 199.15 | J/mol*K | N/A | Aston, Janz, et al., 1951 | DH |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
171.04 | 298.15 | Aston, Janz, et al., 1951 | T = 15 to 298 K.; DH |
Gas Chromatography
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | SLB-5MS | 645. | Risticevic, Carasek, et al., 2008 | 10. m/0.18 mm/0.18 μm, Helium, 40. C @ 1.5 min, 10. K/min; Tend: 295. C |
Capillary | OV-101 | 594. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
References
Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Aston, Rock, et al., 1952
Aston, J.G.; Rock, E.J.; Isserow, S.,
The heats of combustion of the methyl substituted hydrazines and some observations on the burning of volatile liquids,
J. Am. Chem. Soc., 1952, 74, 2484-24. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Aston, Janz, et al., 1951
Aston, J.G.; Janz, G.J.; Russell, K.E.,
The heat capacity, heats of fusion and vaporization, vapor pressures and entropy of symmetrical dimethylhydrazine,
J. Am. Chem. Soc., 1951, 73, 1943-1945. [all data]
Risticevic, Carasek, et al., 2008
Risticevic, S.; Carasek, E.; Pawliszyn, J.,
Headspace solid-phase microextraction-gas chromatographic-time-of-flight mass spectrometric methodology for geographical origin verification of coffee,
Anal. Chim. Acta, 2008, 617, 1-2, 72-84, https://doi.org/10.1016/j.aca.2008.04.009
. [all data]
Zenkevich, 2005
Zenkevich, I.G.,
Experimentally measured retention indices., 2005. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions ΔcH°liquid Enthalpy of combustion of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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