Methanimine

• Formula: CH₃N
• Molecular weight: 29.0412
• IUPAC Standard InChI: InChI=1S/CH3N/c1-2/h2H,1H2 Copy

  
• IUPAC Standard InChIKey: WDWDWGRYHDPSDS-UHFFFAOYSA-N Copy
• CAS Registry Number: 2053-29-4
• Chemical structure:
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• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH₂N^- +  =

By formula: CH₂N^- + H⁺ = CH₃N

(CAS Reg. No. 54448-39-4 • 4294967295) +  = CAS Reg. No. 54448-39-4

By formula: (CAS Reg. No. 54448-39-4 • 4294967295CH₃N) + CH₃N = CAS Reg. No. 54448-39-4

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Peerboom, Ingemann, et al., 1990
Peerboom, R.A.L.; Ingemann, S.; Nibbering, N.M.M.; Liebman, J.F., Proton affinities and heats of formation of the imines CH₂=NH, CH₂=NMe and PhCH=NH, J. Chem. Soc. Perkin Trans. 2, 1990, 1825-1828. [all data]

Grela and Colussi, 1988
Grela, M.A.; Colussi, A.J., Decomposition of methylamino and aminomethyl radicals. The heats of formation of methyleneimine (CH₂=NH) and hydrazyl (N₂H₃) radical, Int. J. Chem. Kinet., 1988, 20, 713-718. [all data]

DeFrees and Hehre, 1978
DeFrees, D.J.; Hehre, W.J., Methyleneimine, J. Phys. Chem., 1978, 82, 391-393. [all data]

Kass and DePuy, 1985
Kass, S.R.; DePuy, C.H., Gas phase ion chemistry of azides. The generation of CH=N^- and CH₂=NCH₂^-, J. Org. Chem., 1985, 50, 2874. [all data]

MacKay, Hemsworth, et al., 1976
MacKay, G.J.; Hemsworth, R.S.; Bohme, D.K., Absolute gas-phase acidities of CH₃NH₂, C₂H₅NH₂, (CH₃)₂NH, and (CH₃)₃N, Can. J. Chem., 1976, 54, 1624. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References

• Symbols used in this document:
  

  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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