NO2+
- Formula: NO2+
- Molecular weight: 46.0050
- CAS Registry Number: 14522-82-8
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Reaction thermochemistry data
Go To: Top, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: NO2+ + N2O = (NO2+ • N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.0 | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 72.8 | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrH° | 55. ± 3. | kJ/mol | DT | Illies, 1988 | gas phase; ΔrH(0 K)=55.7 kJ/mol |
ΔrH° | 54.8 | kJ/mol | PI | Linn and Ng, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrS° | 51.9 | J/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=55.7 kJ/mol |
By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92. | J/mol*K | N/A | Hiraoka, Fujimaki, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12. | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 23. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21. | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 24. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 75. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.0 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 86.2 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 87.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 90.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 108. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 74.9 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 88. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: NO2+ + N2 = (NO2+ • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 76.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: NO2+ + H2O = (NO2+ • H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
67.4 (+9.6,-0.) | PD/KERD | Graul, Kim, et al., 1992 | gas phase |
Ion clustering data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: NO2+ + H2O = (NO2+ • H2O)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
67.4 (+9.6,-0.) | PD/KERD | Graul, Kim, et al., 1992 | gas phase |
By formula: NO2+ + N2O = (NO2+ • N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.0 | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 72.8 | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrH° | 55. ± 3. | kJ/mol | DT | Illies, 1988 | gas phase; ΔrH(0 K)=55.7 kJ/mol |
ΔrH° | 54.8 | kJ/mol | PI | Linn and Ng, 1981 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
ΔrS° | 51.9 | J/mol*K | DT | Illies, 1988 | gas phase; ΔrH(0 K)=55.7 kJ/mol |
By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21. | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 24. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 75. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12. | kJ/mol | EI | Cameron, Aitken, et al., 1994 | gas phase |
ΔrH° | 23. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 88. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92. | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase |
By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16. | kJ/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92. | J/mol*K | N/A | Hiraoka, Fujimaki, et al., 1994 | gas phase; Entropy change calculated or estimated |
By formula: NO2+ + N2 = (NO2+ • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 76.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 87.4 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 16. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 90.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 108. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 71.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 74.9 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.1 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 86.2 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.8 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6. ± 1. | kJ/mol | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.0 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1989 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W.,
Appearence Energies of Small Cluster Ions and their Fragments,
J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935
. [all data]
Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S.,
Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O,
J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524
. [all data]
Illies, 1988
Illies, A.J.,
Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures,
J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037
. [all data]
Linn and Ng, 1981
Linn, S.H.; Ng, C.Y.,
Photoionization Study of CO2, N2O Dimers and Clusters,
J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931
. [all data]
Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S.,
How are Nitrogen Molecules Bound to NO2+ and NO+?,
J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880
. [all data]
Graul, Kim, et al., 1992
Graul, S.T.; Kim, H.S.; Bowers, M.T.,
The Dynamics of Photodissociation of the Gas Phase (N2O.H2O)+ Cluster Ion,
Int. J. Mass Spectrom. Ion Proc., 1992, 117, 507, https://doi.org/10.1016/0168-1176(92)80111-D
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Ion clustering data, References
- Symbols used in this document:
T Temperature ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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