NO2+


Reaction thermochemistry data

Go To: Top, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

NO2+ + Nitrous oxide = (NO2+ • Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ • N2O)

Quantity Value Units Method Reference Comment
Δr59.0kJ/molEICameron, Aitken, et al., 1994gas phase
Δr72.8kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr55. ± 3.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol
Δr54.8kJ/molPILinn and Ng, 1981gas phase
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr51.9J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol

(NO2+ • 5Nitrous oxide) + Nitrous oxide = (NO2+ • 6Nitrous oxide)

By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)

Quantity Value Units Method Reference Comment
Δr16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

(NO2+ • 2Nitrous oxide) + Nitrous oxide = (NO2+ • 3Nitrous oxide)

By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)

Quantity Value Units Method Reference Comment
Δr12.kJ/molEICameron, Aitken, et al., 1994gas phase
Δr23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • Nitrous oxide) + Nitrous oxide = (NO2+ • 2Nitrous oxide)

By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)

Quantity Value Units Method Reference Comment
Δr21.kJ/molEICameron, Aitken, et al., 1994gas phase
Δr24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 10Nitrogen) + Nitrogen = (NO2+ • 11Nitrogen)

By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr77.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 11Nitrogen) + Nitrogen = (NO2+ • 12Nitrogen)

By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 9Nitrogen) + Nitrogen = (NO2+ • 10Nitrogen)

By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr86.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 2Nitrogen) + Nitrogen = (NO2+ • 3Nitrogen)

By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr18. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 3Nitrogen) + Nitrogen = (NO2+ • 4Nitrogen)

By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 4Nitrogen) + Nitrogen = (NO2+ • 5Nitrogen)

By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 5Nitrogen) + Nitrogen = (NO2+ • 6Nitrogen)

By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 6Nitrogen) + Nitrogen = (NO2+ • 7Nitrogen)

By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 7Nitrogen) + Nitrogen = (NO2+ • 8Nitrogen)

By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 8Nitrogen) + Nitrogen = (NO2+ • 9Nitrogen)

By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr79.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • Nitrogen) + Nitrogen = (NO2+ • 2Nitrogen)

By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 3Nitrous oxide) + Nitrous oxide = (NO2+ • 4Nitrous oxide)

By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)

Quantity Value Units Method Reference Comment
Δr18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 4Nitrous oxide) + Nitrous oxide = (NO2+ • 5Nitrous oxide)

By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)

Quantity Value Units Method Reference Comment
Δr17.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

NO2+ + Nitrogen = (NO2+ • Nitrogen)

By formula: NO2+ + N2 = (NO2+ • N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

NO2+ + Water = (NO2+ • Water)

By formula: NO2+ + H2O = (NO2+ • H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.4 (+9.6,-0.) PD/KERDGraul, Kim, et al., 1992gas phase

Ion clustering data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

NO2+ + Water = (NO2+ • Water)

By formula: NO2+ + H2O = (NO2+ • H2O)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
67.4 (+9.6,-0.) PD/KERDGraul, Kim, et al., 1992gas phase

NO2+ + Nitrous oxide = (NO2+ • Nitrous oxide)

By formula: NO2+ + N2O = (NO2+ • N2O)

Quantity Value Units Method Reference Comment
Δr59.0kJ/molEICameron, Aitken, et al., 1994gas phase
Δr72.8kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr55. ± 3.kJ/molDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol
Δr54.8kJ/molPILinn and Ng, 1981gas phase
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Δr51.9J/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=55.7 kJ/mol

(NO2+ • Nitrous oxide) + Nitrous oxide = (NO2+ • 2Nitrous oxide)

By formula: (NO2+ • N2O) + N2O = (NO2+ • 2N2O)

Quantity Value Units Method Reference Comment
Δr21.kJ/molEICameron, Aitken, et al., 1994gas phase
Δr24.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr75.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 2Nitrous oxide) + Nitrous oxide = (NO2+ • 3Nitrous oxide)

By formula: (NO2+ • 2N2O) + N2O = (NO2+ • 3N2O)

Quantity Value Units Method Reference Comment
Δr12.kJ/molEICameron, Aitken, et al., 1994gas phase
Δr23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 3Nitrous oxide) + Nitrous oxide = (NO2+ • 4Nitrous oxide)

By formula: (NO2+ • 3N2O) + N2O = (NO2+ • 4N2O)

Quantity Value Units Method Reference Comment
Δr18.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 4Nitrous oxide) + Nitrous oxide = (NO2+ • 5Nitrous oxide)

By formula: (NO2+ • 4N2O) + N2O = (NO2+ • 5N2O)

Quantity Value Units Method Reference Comment
Δr17.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr92.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994gas phase

(NO2+ • 5Nitrous oxide) + Nitrous oxide = (NO2+ • 6Nitrous oxide)

By formula: (NO2+ • 5N2O) + N2O = (NO2+ • 6N2O)

Quantity Value Units Method Reference Comment
Δr16.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AHiraoka, Fujimaki, et al., 1994gas phase; Entropy change calculated or estimated

NO2+ + Nitrogen = (NO2+ • Nitrogen)

By formula: NO2+ + N2 = (NO2+ • N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • Nitrogen) + Nitrogen = (NO2+ • 2Nitrogen)

By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)

Quantity Value Units Method Reference Comment
Δr19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 2Nitrogen) + Nitrogen = (NO2+ • 3Nitrogen)

By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)

Quantity Value Units Method Reference Comment
Δr18. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 3Nitrogen) + Nitrogen = (NO2+ • 4Nitrogen)

By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)

Quantity Value Units Method Reference Comment
Δr16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 4Nitrogen) + Nitrogen = (NO2+ • 5Nitrogen)

By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)

Quantity Value Units Method Reference Comment
Δr14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 5Nitrogen) + Nitrogen = (NO2+ • 6Nitrogen)

By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)

Quantity Value Units Method Reference Comment
Δr9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 6Nitrogen) + Nitrogen = (NO2+ • 7Nitrogen)

By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 7Nitrogen) + Nitrogen = (NO2+ • 8Nitrogen)

By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)

Quantity Value Units Method Reference Comment
Δr8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 8Nitrogen) + Nitrogen = (NO2+ • 9Nitrogen)

By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr79.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 9Nitrogen) + Nitrogen = (NO2+ • 10Nitrogen)

By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)

Quantity Value Units Method Reference Comment
Δr7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr86.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 10Nitrogen) + Nitrogen = (NO2+ • 11Nitrogen)

By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr77.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(NO2+ • 11Nitrogen) + Nitrogen = (NO2+ • 12Nitrogen)

By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)

Quantity Value Units Method Reference Comment
Δr6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cameron, Aitken, et al., 1994
Cameron, B.R.; Aitken, C.G.; Harland, P.W., Appearence Energies of Small Cluster Ions and their Fragments, J. Chem. Soc. Faraday Trans., 1994, 90, 7, 935, https://doi.org/10.1039/ft9949000935 . [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Sato, T.; Yamabe, S., Gas-Phase Solavtion of NO+, O2+, N2O+, and H3O+ with N2O, J. Chem. Phys., 1994, 101, 5, 4073, https://doi.org/10.1063/1.467524 . [all data]

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Linn and Ng, 1981
Linn, S.H.; Ng, C.Y., Photoionization Study of CO2, N2O Dimers and Clusters, J. Chem. Phys., 1981, 75, 10, 4921, https://doi.org/10.1063/1.441931 . [all data]

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., How are Nitrogen Molecules Bound to NO2+ and NO+?, J. Chem. Phys., 1989, 90, 6, 3268, https://doi.org/10.1063/1.455880 . [all data]

Graul, Kim, et al., 1992
Graul, S.T.; Kim, H.S.; Bowers, M.T., The Dynamics of Photodissociation of the Gas Phase (N2O.H2O)+ Cluster Ion, Int. J. Mass Spectrom. Ion Proc., 1992, 117, 507, https://doi.org/10.1016/0168-1176(92)80111-D . [all data]


Notes

Go To: Top, Reaction thermochemistry data, Ion clustering data, References