Molybdenum, tetrakis[μ-(acetato-O:O')]di-, (Mo-Mo)
- Formula: C8H12Mo2O8
- Molecular weight: 428.10
- IUPAC Standard InChIKey: DOOLFANBWPPEGQ-UHFFFAOYSA-J
- CAS Registry Number: 14221-06-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Molybdenum, tetrakis(μ-acetato)di-, (Mo-Mo); Dimolybdenum tetraacetate; Tetraacetatodimolybdenum; Mo2(O2CCH3)4; Molybdenum, tetrakis[μ-(acetato-O:O')]di-,; tetrakis[μ-(acetato-O:O')]dimolybdenum
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Phase change data
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 165.0 ± 8.4 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Cavell, Garner, et al., 1979. |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
129. ± 1. | 491. | C | Slyusareva, Kondrat'ev, et al., 2008 | |
171. ± 7. | 410. | ME,TE | Carson, 1984 | Based on data from 400. to 420. K. |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY |
NIST MS number | 63590 |
References
Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Cavell, Garner, et al., 1979
Cavell, Kingsley J.; Garner, C. David; Pilcher, Geoffrey; Parkes, Stephen,
Standard enthalpies of formation of the tetra-«65533»-acetato-derivatives of dimolybdenum(II), chromium(II)?molybdenum(II), dichromium(II), and dichromium(II) dihydrate, and di-«65533»-acetato-bis(pentane-2,4-dionato)dimolybdenum(II), and their metal?metal bond enthalpy contributions,
J. Chem. Soc., Dalton Trans., 1979, 11, 1714, https://doi.org/10.1039/dt9790001714
. [all data]
Slyusareva, Kondrat'ev, et al., 2008
Slyusareva, I.V.; Kondrat'ev, Yu.V.; Kozin, A.O.; Belorukova, L.P.,
Vestn. St. Petersburg. Universit. Ser. 4 Fiz. Khim., 2008, 3, 64. [all data]
Carson, 1984
Carson, A.S.,
The molar enthalpy of dehydration of Cr2(O2CCH3)4·2H2O(cr) and the molar enthalpies of sublimation of Cr2(O2CCH3)4(cr), Mo2(O2CCH3)4(cr), and Mo2(O2CCF3)4(cr),
The Journal of Chemical Thermodynamics, 1984, 16, 5, 427-429, https://doi.org/10.1016/0021-9614(84)90198-8
. [all data]
Notes
Go To: Top, Phase change data, Mass spectrum (electron ionization), References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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