1,4-Benzenediamine

• Formula: C₆H₈N₂
• Molecular weight: 108.1411
• IUPAC Standard InChI: InChI=1S/C6H8N2/c7-5-1-2-6(8)4-3-5/h1-4H,7-8H2 Copy

  
• IUPAC Standard InChIKey: CBCKQZAAMUWICA-UHFFFAOYSA-N Copy
• CAS Registry Number: 106-50-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: p-Aminoaniline; p-Benzenediamine; p-Diaminobenzene; p-Phenylenediamine; Benzofur D; BASF Ursol D; C.I. Developer 13; C.I. Oxidation Base 10; C.I. 76060; Developer PF; Durafur Black R; Fouramine D; Fourrine D; Fourrine 1; Fur Black 41867; Fur Brown 41866; Fur Yellow; Furro D; Futramine D; Nako H; Orsin; Pelagol D; Pelagol DR; Pelagol Grey D; Peltol D; Renal PF; Santoflex LC; Tertral D; Ursol D; Zoba Black D; 1,4-Diaminobenzene; 1,4-Phenylenediamine; 4-Aminoaniline; Developer 13; Fenylenodwuamina; Oxidation base 10; Phenylenediamine, para; PARA; PPD; Santoflex IC; USAF EK-394; p-Fenylendiamin; Paraphenylen-diamine; Rodol D; UN 1673; Vulkanox 4020; Aminogen II; NSC 4777
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• Information on this page:
  • Phase change data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Gas phase ion energetics data
  • IR Spectrum
  • UV/Visible spectrum
  • Gas Chromatography
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of fusion

Entropy of fusion

Mass spectrum (electron ionization)

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Bret-Dibat and Lichanot, 1989
Bret-Dibat, P.; Lichanot, A., Proprietes thermodynamiques des isomeres de position de benzenes disubstitues en phase condensee, Thermochim. Acta, 1989, 147, 2, 261, https://doi.org/10.1016/0040-6031(89)85181-0 . [all data]

Rai and Mandal, 1989
Rai, U.S.; Mandal, K.D., Chemistry of organic eutectics and 1:1 addition compound: p-phenylenediamine-catechol system, Thermochim. Acta, 1989, 138, 219. [all data]

Kemula, Buchowski, et al., 1968
Kemula, W.; Buchowski, H.; Pawlowski, W., Effect of the position of substituents in an aromatic ring on R(f) and partition coefficients: II. aromatic amines, Rocz. Chem., 1968, 42, 1951. [all data]

Witschonke, 1954
Witschonke, C.R., Freezing point and purity data for some organic compounds, Anal. Chem., 1954, 26, 562-4. [all data]

Sabbah and Perez, 1997
Sabbah, Raphaël; Perez, Laurence, Energétique des liaisons inter- et intramoléculaires dans les trois isomères du benzènediamine, Can. J. Chem., 1997, 75, 4, 357-364, https://doi.org/10.1139/v97-041 . [all data]

Rai and Mandal, 1990
Rai, U.S.; Mandal, K.D., Chemistry of organic eutectics: p-phenylenediamine-m-nitrobenzoic acid system involving the 1:2 addition compound, Bull. Chem. Soc. Jpn., 1990, 63(5), 1496-1502. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Notes

Go To: Top, Phase change data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  Tboil	Boiling point
  Tfus	Fusion (melting) point
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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