Bicyclo[2.2.2]octa-2,5,7-triene


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap10.3 ± 0.02kcal/molCKusano, 1985 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

3Hydrogen + Bicyclo[2.2.2]octa-2,5,7-triene = Bicyclo[2.2.2]octane

By formula: 3H2 + C8H8 = C8H14

Quantity Value Units Method Reference Comment
Δr-93.78 ± 0.31kcal/molChydTurner, 1964liquid phase; solvent: Acetic acid

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kusano, 1985
Kusano, Kazuhito, Micro conduction calorimeters to measure enthalpies of vaporization, Thermochimica Acta, 1985, 88, 1, 109-120, https://doi.org/10.1016/0040-6031(85)85418-6 . [all data]

Turner, 1964
Turner, R.B., Heat of Hydrogenation of Bicyclo[2.2.2]octa-2,5,7-triene, J. Am. Chem. Soc., 1964, 86, 3586-3587. [all data]


Notes

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