Hydroperoxy radical

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas2.09kJ/molReviewChase, 1998Data last reviewed in September, 1978
Quantity Value Units Method Reference Comment
gas,1 bar229.09J/mol*KReviewChase, 1998Data last reviewed in September, 1978

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 2000.2000. to 6000.
A 26.0096045.87510
B 34.858108.814350
C -16.30060-1.636031
D 3.1104410.098053
E -0.018611-10.17380
F -7.140991-26.90210
G 250.7660266.5260
H 2.0920012.092001
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in September, 1978 Data last reviewed in September, 1978

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
5700. RN/A 
4000.5900.TN/A 
9000. TN/A 
 6600.EN/A 
9000. TN/A 
1200. TN/A missing citation gives an upper limit of kH = 6.8E3 M/atm. In the abstract a range of 1E3 M/atm < kH < 3E3 M/atm is given. The mean value of this range (2E3 M/atm) has been used by missing citation, missing citation, and missing citation.
4600.4800.TN/ACalculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit.

References

Go To: Top, Gas phase thermochemistry data, Henry's Law data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

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