Hydroperoxy radical
- Formula: HO2
- Molecular weight: 33.0067
- IUPAC Standard InChIKey: OUUQCZGPVNCOIJ-UHFFFAOYSA-N
- CAS Registry Number: 3170-83-0
- Chemical structure:
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Gas phase thermochemistry data
Go To: Top, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 2.09 | kJ/mol | Review | Chase, 1998 | Data last reviewed in September, 1978 |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 229.09 | J/mol*K | Review | Chase, 1998 | Data last reviewed in September, 1978 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 2000. | 2000. to 6000. |
---|---|---|
A | 26.00960 | 45.87510 |
B | 34.85810 | 8.814350 |
C | -16.30060 | -1.636031 |
D | 3.110441 | 0.098053 |
E | -0.018611 | -10.17380 |
F | -7.140991 | -26.90210 |
G | 250.7660 | 266.5260 |
H | 2.092001 | 2.092001 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in September, 1978 | Data last reviewed in September, 1978 |
Henry's Law data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
---|---|---|---|---|
5700. | R | N/A | ||
4000. | 5900. | T | N/A | |
9000. | T | N/A | ||
6600. | E | N/A | ||
9000. | T | N/A | ||
1200. | T | N/A | missing citation gives an upper limit of kH = 6.8E3 M/atm. In the abstract a range of 1E3 M/atm < kH < 3E3 M/atm is given. The mean value of this range (2E3 M/atm) has been used by missing citation, missing citation, and missing citation. | |
4600. | 4800. | T | N/A | Calculated from correlation between the polarizabilities and solubilities of stable gases. The temperature dependence is an estimate of the upper limit. |
References
Go To: Top, Gas phase thermochemistry data, Henry's Law data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Henry's Law data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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