trinitromethane
- Formula: CHN3O6
- Molecular weight: 151.0351
- CAS Registry Number: 517-25-9
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tfus | 292. | K | N/A | Lewis and Smyth, 1939 | Uncertainty assigned by TRC = 3. K; TRC |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔvapH° | 54.8 | kJ/mol | V | Carpenter, Zimmer, et al., 1970 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔsubH° | 45.2 ± 2.1 | kJ/mol | N/A | Miroshnichenko and Vorob'eva, 1999 | AC |
| ΔsubH° | 46.0 ± 0.42 | kJ/mol | V | Mirishnichenko, Lebedev, et al., 1967 | Heat of combustion corrected for constant pressure; ALS |
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 32.6 | 303. | A | Stephenson and Malanowski, 1987 | Based on data from 290. to 317. K. See also Miroshnichenko, Lebedev, et al., 1967.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lewis and Smyth, 1939
Lewis, G.L.; Smyth, C.P.,
The Dipole Moments and Structures of Ozone, Silicobromoform and Dichlorogermane,
J. Am. Chem. Soc., 1939, 61, 3067-3070. [all data]
Carpenter, Zimmer, et al., 1970
Carpenter, G.A.; Zimmer, M.F.; Baroody, E.E.; Robb, R.A.,
Enthalpy of formation of bromotrinitromethane,
J. Chem. Eng. Data, 1970, 15, 553-556. [all data]
Miroshnichenko and Vorob'eva, 1999
Miroshnichenko, E.O.; Vorob'eva, V.P.,
Thermochemical characteristics of nitroalkanes,
Zh. Fiz. Khim., 1999, 73, 3, 419. [all data]
Mirishnichenko, Lebedev, et al., 1967
Mirishnichenko, E.A.; Lebedev, Yu.A.; Shevelev, S.A.; Gulevskaya, V.I.; Fainzil'berg, A.A.; Apin, A.Ya.,
Thermochemistry of trinitromethane,
Zh. Fiz. Khim., 1967, 41, 1477-1479. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Miroshnichenko, Lebedev, et al., 1967
Miroshnichenko, E.A.; Lebedev, Yu.A.; Shevelev, S.A.; Gulivskaya, V.I.; Fainzil'berg, A.A.; Apin, A.Ya.,
Zh. Fiz. Khim., 1967, 41, 6, 1477. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tfus Fusion (melting) point ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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