Methanamine, N-methyl-N-nitro-

• Formula: C₂H₆N₂O₂
• Molecular weight: 90.0812
• IUPAC Standard InChI: InChI=1S/C2H6N2O2/c1-3(2)4(5)6/h1-2H3 Copy

  
• IUPAC Standard InChIKey: XRWKADIRZXTTLH-UHFFFAOYSA-N Copy
• CAS Registry Number: 4164-28-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Dimethylnitramine; Dimethylamine, N-nitro-; s-N,N-Dimethyl nitramine; Dimethylnitroamine; N-Nitrodimethylamine; N,N-Dimethylnitramine; (CH3)2NNO2; Dimethylnitramin; DMNO; DMN; N-Nitro-DMA; NSC 137860
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• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • UV/Visible spectrum
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

Enthalpy of fusion

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Bruhl, 1897
Bruhl, J.W., Spectrochemistry of nitrogen containing compounds V, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1897, 22, 373. [all data]

Bradley, Cotson, et al., 1952
Bradley, R.S.; Cotson, S.; Cox, E.G., The determination of vapour pressures of the order of 1 mm of mercury by a mnodification of Smith and Menzie's method. The vapour pressure of dimethylnitramine, J. Chem. Soc., 1952, 740-741. [all data]

Stephen, Bradley, et al., 1952
Stephen, Alistair M.; Bradley, R.S.; Cotson, S.; Cox, E.G.; Gerrard, W.; Thrush, A.M.; Fairfull, A.E.S.; Lowe, J.L.; Peak, D.A., Notes, J. Chem. Soc., 1952, 738, https://doi.org/10.1039/jr9520000738 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]

Zeman, 1997
Zeman, Svatopluk, Some predictions in the field of the physical thermal stability of nitramines, Thermochimica Acta, 1997, 302, 1-2, 11-16, https://doi.org/10.1016/S0040-6031(96)03101-2 . [all data]

Oyumi and Brill, 1987
Oyumi, Y.; Brill, T.B., Thermal decomposition of energetic materials. 23. Thermochemical differentiation of cyclic and acyclic nitramines by their phase transitions, Thermochim. Acta, 1987, 116, 125-130. [all data]

Notes

Go To: Top, Phase change data, References

• Symbols used in this document:
  

  Tboil	Boiling point
  Tfus	Fusion (melting) point
  ΔfusH	Enthalpy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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