Nitric oxide anion
- Formula: NO-
- Molecular weight: 30.0066
- IUPAC Standard InChIKey: FZRKAZHKEDOPNN-UHFFFAOYSA-N
- CAS Registry Number: 14967-78-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: NO-; Nitrogen oxide, ion
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 71
- Ion clustering data
- Constants of diatomic molecules
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
EAneutral (eV) | Method | Reference | Comment |
---|---|---|---|
0.040 ± 0.010 | N/A | Velarde, Habteyes, et al., 2007 | |
0.0260 ± 0.0050 | LPES | Travers, Cowles, et al., 1989 | ground state triplet anion |
0.024 ± 0.010 | LPES | Siegel, Celotta, et al., 1972 | |
0.02 ± 0.10 | CIDT | Tiernan and Wu, 1978 | |
0.0250 ± 0.0070 | ETS | Burrow, 1974 | |
0.10 ± 0.10 | ECD | Chen and Wentworth, 1983 | |
0.02 ± 0.10 | Endo | Hughes, Lifschitz, et al., 1973 | |
0.026 ± 0.022 | Kine | Parkes and Sugden, 1972 | |
0.68 ± 0.20 | Endo | Refaey, 1976 | |
>0.10 ± 0.10 | NBIE | Nalley, Compton, et al., 1973 | |
>0.089982 | Endo | Berkowitz, Chupka, et al., 1971 | |
>0.06 ± 0.10 | Endo | Chantry, 1971 | |
>0.65 ± 0.10 | EIAE | Stockdale, Compton, et al., 1969 | From NO2 |
0.85 ± 0.10 | EIAE | Williams and Hamill, 1968 | From EtONO, nBuONO |
0.828255 | SI | Page and Goode, 1969 | The Magnetron method, lacking mass analysis, is not considered reliable. |
0.910647 | SI | Farragher, Page, et al., 1964 | The Magnetron method, lacking mass analysis, is not considered reliable. |
Protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1511.6 ± 0.63 | kJ/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1484.0 ± 1.4 | kJ/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Velarde, Habteyes, et al., 2007
Velarde, L.; Habteyes, T.; Grumbling, E.R.; Pichugin, K.; Sanov, A.,
Solvent resonance effect on the anisotropy of NO-(N2O)(n) cluster anion photodetachment,
J. Chem. Phys., 2007, 127, 8, 084302, https://doi.org/10.1063/1.2766948
. [all data]
Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B.,
Reinvestigation of the Electron Affinities of O2 and NO,
Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6
. [all data]
Siegel, Celotta, et al., 1972
Siegel, M.W.; Celotta, R.J.; Hall, J.L.; Levine, J.; Bennett, R.A.,
Molecular Photodetachment Spectroscopy. I. The Electron Affinity of Nitric Oxide and the Molecular Constants of NO-,
Phys. Rev. A, 1972, 6, 2, 607, https://doi.org/10.1103/PhysRevA.6.607
. [all data]
Tiernan and Wu, 1978
Tiernan, T.O.; Wu, R.L.C.,
Thermochemical Data for Molecular Negative Ions from Collisional Dissociation Thresholds,
Adv. Mass Spectrom., 1978, 7A, 136. [all data]
Burrow, 1974
Burrow, P.D.,
Temporary negative ion formation in NO and O2,
Chem. Phys. Lett., 1974, 26, 265. [all data]
Chen and Wentworth, 1983
Chen, E.C.M.; Wentworth, W.E.,
Determination of molecular electron affinities using the electron capture detector in the pulse sampling mode at steady state,
J. Phys. Chem., 1983, 87, 45. [all data]
Hughes, Lifschitz, et al., 1973
Hughes, B.M.; Lifschitz, C.; Tiernan, T.O.,
Electron affinities from endothermic negative-ion charge-transfer reactions. III. NO, NO2, S2, CS2, Cl2, Br2, I2, and C2H,
J. Chem. Phys., 1973, 59, 3162. [all data]
Parkes and Sugden, 1972
Parkes, D.A.; Sugden, T.M.,
Electron attachment and detachment in nitric oxide,
J. Chem. Soc. Faraday Trans. 2, 1972, 68, 600. [all data]
Refaey, 1976
Refaey, K.M.A.,
Endoergic ion-molecule-Collision Processes of Negative Ions. IV. Collisions of I- on NO2, N2O and NO,
Int. J. Mass Spectrom. Ion Phys., 1976, 21, 21. [all data]
Nalley, Compton, et al., 1973
Nalley, S.J.; Compton, R.N.; Schweinler, H.C.; Anderson, V.E.,
Molecular electron affinities from collisional ionization of cesium. I. NO, NO2, and N2O,
J. Chem. Phys., 1973, 59, 4125. [all data]
Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Gutman, D.,
Electron Affinities of O2, O3, NO, NO2, and NO3 by Endothermic Charge Transfer,
J. Chem. Phys., 1971, 55, 6, 2733, https://doi.org/10.1063/1.1676488
. [all data]
Chantry, 1971
Chantry, P.J.,
Doppler broadening in beam experiments,
J. Chem. Phys., 1971, 55, 2746. [all data]
Stockdale, Compton, et al., 1969
Stockdale, J.A.D.; Compton, R.N.; Hurst, G.S.; Reinhardt, P.W.,
Collisions of Monoenergetic Electrons with NO2: Possible Lower Limits to the Electron Affinities of O2 and NO,
J. Chem. Phys., 1969, 50, 5, 2176, https://doi.org/10.1063/1.1671347
. [all data]
Williams and Hamill, 1968
Williams, J.M.; Hamill, W.H.,
Ionization potentials of molecules and free radicals and appearance potentials by electron impact in the mass spectrometer,
J. Chem. Phys., 1968, 49, 4467. [all data]
Page and Goode, 1969
Page, F.M.; Goode, G.C.,
Negative Ions and the Magnetron., Wiley, NY, 1969. [all data]
Farragher, Page, et al., 1964
Farragher, A.L.; Page, F.M.; Wheeler, R.C.,
Electron Affinities of the Nitrogen Oxides,
Disc. Faraday Soc., 1964, 37, 203, https://doi.org/10.1039/df9643700203
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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