Bismuthine, triethyl-
- Formula: C6H15Bi
- Molecular weight: 296.1637
- IUPAC Standard InChI: InChI=1S/3C2H5.Bi/c3*1-2;/h3*1H2,2H3;
- IUPAC Standard InChIKey: FPYOWXFLVWSKPS-UHFFFAOYSA-N
- CAS Registry Number: 617-77-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Triethylbismuth; triethylbismuthine
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | 170. ± 17. | kJ/mol | Review | Martinho Simões | MS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -4961. ± 17. | kJ/mol | CC-SB | Lautsch, Tröber, et al., 1963 | Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid | 379.0 | J/mol*K | N/A | Nistratov, Rabinovich, et al., 1989 | DH |
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 242.2 | 298.15 | Nistratov, Rabinovich, et al., 1989 | T = 5 to 330 K. Cp data also given for the glassy state (0-94.8 K) and the supercooled liquid (94.8-145.8 K). T(glass) = 94.8 K.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R.,
Z. Chem., 1963, 3, 415. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Nistratov, Rabinovich, et al., 1989
Nistratov, V.P.; Rabinovich, I.B.; Sheiman, M.S.; Smirnova, N.N.; Zelyaev, I.A.; Feshchenko, I.A.,
Specific heat and thermodyanamic characteristics of triethylbismuth,
Zhur. Fiz. Khim., 1989, 63, 1779-1783. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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