Tetraethylgermanium

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-45.08 ± 0.93kcal/molReviewMartinho SimõesMS
Δfliquid-48.8 ± 1.8kcal/molReviewMartinho SimõesMS
Δfliquid-50.3 ± 1.6kcal/molReviewMartinho SimõesSelected data.; MS
Δfliquid-48.4 ± 1.1kcal/molReviewMartinho SimõesMS
Quantity Value Units Method Reference Comment
Δcliquid-1516.0 ± 1.0kcal/molCC-SBShaulov, Federov, et al., 1969MS
Δcliquid-1517.8 ± 1.5kcal/molCC-RBBills and Cotton, 1964Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Δcliquid-1519.3 ± 0.76kcal/molCC-SBPope and Skinner, 1964Please also see Cox and Pilcher, 1970.; MS
Δcliquid-1515.6 ± 1.7kcal/molCC-SBRabinovich, Tel'noi, et al., 1963Please also see Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
liquid102.5cal/mol*KN/ARabinovich, Sheiman, et al., 1985DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
70.43298.15Rabinovich, Sheiman, et al., 1985T = 8 to 300 K.; DH
74.00298.15Maslova, Rabinovich, et al., 1972T = 60 to 300 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Shaulov, Federov, et al., 1969
Shaulov, Yu.Kh.; Federov, A.K.; Genchel, V.G., Russ. J. Phys. Chem., 1969, 43, 744. [all data]

Bills and Cotton, 1964
Bills, J.L.; Cotton, F.A., J. Phys. Chem., 1964, 68, 806. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Pope and Skinner, 1964
Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 12.?Heat of combustion of tetraethyl germanium and of tetrapropyl germanium, Trans. Faraday Soc., 1964, 60, 1404, https://doi.org/10.1039/tf9646001404 . [all data]

Rabinovich, Tel'noi, et al., 1963
Rabinovich, I.B.; Tel'noi, V.I.; Karyakin, N.V.; Razuvaev, G.A., Dokl. Akad. Nauk SSSR, 1963, 149, 324. [all data]

Rabinovich, Sheiman, et al., 1985
Rabinovich, I.B.; Sheiman, M.S.; Nistratov, V.P.; Kamelova, G.P.; Zorin, A.D., The heat capacity and thermodynamic characteristics of tetraethylgermane, Zhur. Fiz. Khim., 1985, 59, 2414-2417. [all data]

Maslova, Rabinovich, et al., 1972
Maslova, V.A.; Rabinovich, I.B.; Nistoalov, V.P.; Faminskaya, L.A., Specific heat and phase transitions of some alkyl compounds of silicon, germanium, and tin, Tr. Khim. Khim. Tekhnol., 1972, (2), 44-50. [all data]


Notes

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