Diadamantane
- Formula: C14H20
- Molecular weight: 188.3086
- CAS Registry Number: 2292-79-7
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -241.9 ± 2.3 | kJ/mol | Ccb | Clark, Knox, et al., 1979 | Gas flow technique for Hs, see Clark, Knox, et al., 1975 AND Carson, Laye, et al., 1971; ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -8125.6 ± 2.6 | kJ/mol | Ccb | Clark, Knox, et al., 1979 | Gas flow technique for Hs, see Clark, Knox, et al., 1975 AND Carson, Laye, et al., 1971; Corresponding ΔfHºsolid = -241.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 200.16 | J/mol*K | N/A | Westrum, McKervey, et al., 1978 | crystaline, III phase; DH |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
220.2 | 295.56 | Spinella, Andrews, et al., 1978 | crystaline, III phase; T = 295 to 540 K. Value is unsmoothed experimental datum.; DH |
223.22 | 298.15 | Westrum, McKervey, et al., 1978 | crystaline, III phase; T = 5 to 350 K. Data between 350 and 540 K taken from other work.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Clark, Knox, et al., 1979
Clark, T.; Knox, T.M.O.; McKervey, M.A.; Mackle, H.; Rooney, J.J.,
Thermochemistry of bridged-ring substances. Enthalpies of formation of some diamondoid hydrocarbons and of perhydroquinacene. Comparisons with data from empirical force field calculations,
J. Am. Chem. Soc., 1979, 101, 2404-2410. [all data]
Clark, Knox, et al., 1975
Clark, T.; Knox, T.M.; Mackle, H.; McKervey, M.A.; Rooney, J.J.,
Calorimetric evaluation of enthalpies of formation of some bridged-ring hydrocarbons. Comparison with data from empirical force field calculations.,
J. Am. Chem. Soc., 1975, 97, 3835-3836. [all data]
Carson, Laye, et al., 1971
Carson, A.S.; Laye, P.G.; Steele, W.V.; Johnson, D.E.; McKervey, M.A.,
The enthalpy of formation of diamantane,
J. Chem. Thermodyn., 1971, 3, 915-918. [all data]
Westrum, McKervey, et al., 1978
Westrum, E.F., Jr.; McKervey, M.A.; Andrews, J.T.S.; Fort, R.C., Jr.; Clark, T.,
Heat capacity and thermodynamic properties of diamantane from 5 to 540 K,
J. Chem. Thermodynam., 1978, 10, 959-965. [all data]
Spinella, Andrews, et al., 1978
Spinella, G.M.; Andrews, J.T.S.; Bacon, W.E.,
Diamantane: heat capacity (300 to 540 K) and thermodynamics of transition and fusion,
J. Chem. Thermodynam., 1978, 10, 1023-1032. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,solid Constant pressure heat capacity of solid S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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