Diadamantane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-241.9 ± 2.3kJ/molCcbClark, Knox, et al., 1979Gas flow technique for Hs, see Clark, Knox, et al., 1975 AND Carson, Laye, et al., 1971; ALS
Quantity Value Units Method Reference Comment
Δcsolid-8125.6 ± 2.6kJ/molCcbClark, Knox, et al., 1979Gas flow technique for Hs, see Clark, Knox, et al., 1975 AND Carson, Laye, et al., 1971; Corresponding Δfsolid = -241.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
solid,1 bar200.16J/mol*KN/AWestrum, McKervey, et al., 1978crystaline, III phase; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
220.2295.56Spinella, Andrews, et al., 1978crystaline, III phase; T = 295 to 540 K. Value is unsmoothed experimental datum.; DH
223.22298.15Westrum, McKervey, et al., 1978crystaline, III phase; T = 5 to 350 K. Data between 350 and 540 K taken from other work.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clark, Knox, et al., 1979
Clark, T.; Knox, T.M.O.; McKervey, M.A.; Mackle, H.; Rooney, J.J., Thermochemistry of bridged-ring substances. Enthalpies of formation of some diamondoid hydrocarbons and of perhydroquinacene. Comparisons with data from empirical force field calculations, J. Am. Chem. Soc., 1979, 101, 2404-2410. [all data]

Clark, Knox, et al., 1975
Clark, T.; Knox, T.M.; Mackle, H.; McKervey, M.A.; Rooney, J.J., Calorimetric evaluation of enthalpies of formation of some bridged-ring hydrocarbons. Comparison with data from empirical force field calculations., J. Am. Chem. Soc., 1975, 97, 3835-3836. [all data]

Carson, Laye, et al., 1971
Carson, A.S.; Laye, P.G.; Steele, W.V.; Johnson, D.E.; McKervey, M.A., The enthalpy of formation of diamantane, J. Chem. Thermodyn., 1971, 3, 915-918. [all data]

Westrum, McKervey, et al., 1978
Westrum, E.F., Jr.; McKervey, M.A.; Andrews, J.T.S.; Fort, R.C., Jr.; Clark, T., Heat capacity and thermodynamic properties of diamantane from 5 to 540 K, J. Chem. Thermodynam., 1978, 10, 959-965. [all data]

Spinella, Andrews, et al., 1978
Spinella, G.M.; Andrews, J.T.S.; Bacon, W.E., Diamantane: heat capacity (300 to 540 K) and thermodynamics of transition and fusion, J. Chem. Thermodynam., 1978, 10, 1023-1032. [all data]


Notes

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