Phosgene

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
liquid192.80J/mol*KN/AGiauque and Ott, 1960Data for liquid from 48GIA/JON.
liquid198.11J/mol*KN/AGiauque and Jones, 1948A value of S0 of 6.82 J/mol*K has been added to the calorimetric value of S280-S0.

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
102.59160.55Giauque and Ott, 1960T = 13 to 160 K. Value is unsmoothed experimental datum.
100.79280.Giauque and Jones, 1948T = 15 to 280 K.

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Giauque and Ott, 1960
Giauque, W.F.; Ott, J.B., The three melting points and heats of fusion of phosgene. Entropy of solids I and II, and atomic exchange disorder in solid II, J. Am. Chem. Soc., 1960, 82, 2689-2695. [all data]

Giauque and Jones, 1948
Giauque, W.F.; Jones, W.M., Carbonyl chloride. Entropy. Heat capacity. Vapor pressure. Heats of fusion and vaporization. Comments on solid sulfur dioxide structure, J. Am. Chem. Soc., 1948, 70, 120-124. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References