Sorbitol

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-1353.7 ± 1.4kJ/molCcbGerasimov, Blokh, et al., 1985ALS
Quantity Value Units Method Reference Comment
Δcsolid-3009.4 ± 1.4kJ/molCcbGerasimov, Blokh, et al., 1985Corresponding Δfsolid = -1352.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
241.43298.15Lian, Chen, et al., 1982DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus366.5KN/ABarone, DellaGatta, et al., 1990Uncertainty assigned by TRC = 0.6 K; TRC
Tfus371.85KN/AQuinquenet, Ollivon, et al., 1988Uncertainty assigned by TRC = 0.5 K; m.p. of the .gamma., presumably stable, form; TRC
Tfus361.25KN/AQuinquenet, Ollivon, et al., 1988Metastable crystal phase; Uncertainty assigned by TRC = 0.5 K; m.p. of the A (presumably metastable) form; TRC
Tfus367.45KN/AQuinquenet, Ollivon, et al., 1988Metastable crystal phase; Uncertainty assigned by TRC = 1. K; this is m.p. of the B, presumably a metastable, form; TRC
Quantity Value Units Method Reference Comment
Δsub186.kJ/molBBarone, Gatta, et al., 1990AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
132.4 ± 2.0477.TEBarone, Gatta, et al., 1990Based on data from 461. to 497. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
30.200366.5N/ABarone and Della Gatta, 1990DH
30.35369.2ACTong, Tan, et al., 2008Based on data from 80. to 390. K.; AC
30.2366.5DSCDomalski and Hearing, 1996See also Barone, Gatta, et al., 1990.; AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
82.5366.5Barone and Della Gatta, 1990DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gerasimov, Blokh, et al., 1985
Gerasimov, P.A.; Blokh, E.L.; Gubareva, A.I., Standard heats of formation of intermediates in the synthesis of vitamin C, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1985, 28, 54-56. [all data]

Lian, Chen, et al., 1982
Lian, Y.N.; Chen, A.T.; Suurkuusk, J.; Wadsoe, I., Polyol-water interactions as reflected by aqueous heat capacity values, Acta Chem. Scand., 1982, A36(9), 735-739. [all data]

Barone, DellaGatta, et al., 1990
Barone, G.; DellaGatta, G.; Ferro, D.; Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86, 75. [all data]

Quinquenet, Ollivon, et al., 1988
Quinquenet, S.; Ollivon, M.; Grabielle-Madelmont, C.; Serpelloni, M., Polymorphism of Hydrated Sorbitol, Thermochim. Acta, 1988, 125, 125. [all data]

Barone, Gatta, et al., 1990
Barone, Guido; Gatta, Giuseppe Della; Ferro, Daniela; Piacente, Vincenzo, Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, Faraday Trans., 1990, 86, 1, 75, https://doi.org/10.1039/ft9908600075 . [all data]

Barone and Della Gatta, 1990
Barone, G.; Della Gatta, G., Ferro D., and Piacente, V., Enthalpies and entropies of sublimation, vaporization and fusion of nine polyhydric alcohols, J. Chem. Soc., Faraday Trans., 1990, 86(1), 75-79. [all data]

Tong, Tan, et al., 2008
Tong, B.; Tan, Z.C.; Shi, Q.; Li, Y.S.; Wang, S.X., Thermodynamic investigation of several natural polyols (II), J Therm Anal Calorim, 2008, 91, 2, 463-469, https://doi.org/10.1007/s10973-007-8361-8 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, References